- 5.5.28: Draw the structure of (a) a five-carbon alkene that would give the ...
- 5.5.29: Give the missing reactant or product in each of the following equat...
- 5.5.3: Outline a laboratory preparation of each of the following compounds...
- 5.5.31: Deuterium (D, or 2 H) is an isotope of hydrogen with atomic mass 5 ...
- 5.5.32: Using the mechanism of halogen addition to alkenes to guide you, pr...
- 5.5.33: Using the mechanism of the oxymercuration reaction to guide you, pr...
- 5.5.34: In the addition of HBr to 3,3-dimethyl-1-butene, the results observ...
- 5.5.35: Give the structures of both the reactive intermediate and the produ...
- 5.5.36: Trifluoroiodomethane undergoes an addition to alkenes in the presen...
- 5.5.37: In thermal cracking (Sec. 5.8), bonds generally break homolytically...
- 5.5.38: (a) What product would be obtained from the ozonolysis of natural r...
- 5.5.39: Free-radical addition of thiols (molecules with the general structu...
- 5.5.4: Although the addition of HCN to an alkene could be envisioned to oc...
- 5.5.41: The halogenation of methane in the gas phase is an industrial metho...
- 5.5.42: Polypropylene carbonate is considered to be a green polymer because...
- 5.5.43: The mechanism for the free-radical polymerization of ethylene shown...
- 5.5.44: (a) Draw the structure of polystyrene, the polymer obtained from th...
- 5.5.45: In a laboratory a bottle was found containing a clear liquid A. The...
- 5.5.46: A compound A with the molecular formula C8H16 decolorized Br2 in CH...
- 5.5.47: Using the curved-arrow or fishhook notation, as appropriate, sugges...
- 5.5.48: Consider the reaction of a methyl radical (?CH3) with the p bond of...
- 5.5.49: Equations 5.25ac on p. 193 show the formation of trialkylboranes fr...
- 5.5.5: When trans-3-hexene is subjected to ozonolysis in the presence of a...
- 5.5.51: Isobutylene (2-methylpropene) can be polymerized by treating it wit...
- 5.5.52: In the sequence shown in Fig. P5.54, the second reaction is unfamil...
Solutions for Chapter 5: AddiTion REACTions of AlkEnEs
Full solutions for Organic Chemistry | 6th Edition
The conjugate base of acetylene or any terminal alkyne.
Attraction between unlike molecules. (11.3)
A basic nitrogen-containing compound of plant origin, many of which are physiologically active when administered to humans.
A carbocation in which an allylic carbon bears the positive charge.
Particles that are identical to helium-4 nuclei, consisting of two protons and two neutrons, symbol 4 2He or 4 2a. (Section 21.1)
A polyaromatic amide; a polymer in which the monomer units are an aromatic diamine and an aromatic dicarboxylic acid
A unit of pressure equal to 760 torr; 1 atm = 101.325 kPa. (Section 10.2) atom The smallest representative particle of an element. (Sections 1.1 and 2.1)
atomic number (Z).
The number of protons in the nucleus of an atom. (2.3)
bonding atomic radius
The radius of an atom as defined by the distances separating it from other atoms to which it is chemically bonded. (Section 7.3)
The cycle that relates lattice energies of ionic compounds to ionization energies, electron affinities, heats of sublimation and formation, and bond enthalpies. (9.3)
A rule that states that it is not possible for a bridgehead carbon of a bicyclic system to possess a carbon carbon double bond if it involves a trans p bond being incorporated in a ring comprised of fewer than eight atoms.
A unit of energy; it is the amount of energy needed to raise the temperature of 1 g of water by 1 °C from 14.5 °C to 15.5 °C. A related unit is the joule: 1 cal = 4.184 J. (Section 5.1)
DEPT 13C NMR
In 13C NMR spectroscopy, a technique that utilizes two rf radiation emitters and provides information regarding the number of protons attached to each carbon atom in a compound.
A molecule with one end having a partial negative charge and the other end having a partial positive charge; a polar molecule. (Section 8.4)
A unimolecular b-elimination reaction
A voltaic cell that utilizes the oxidation of a conventional fuel, such as H2 or CH4, in the cell reaction. (Section 20.7)
gas chromatograph – mass spectrometer
A device used for the analysis of a mixture that contains several compounds.
An electron-pair donor. (Section 16.11)
A chemical formula that indicates the actual number of atoms of each element in one molecule of a substance. (Section 2.6)
The product formed when a nucleoside is coupled to a phosphate group