- 22.214.171.124: Give the structure of (a) a phosphatidylserine; (b) a lecithin.
- 126.96.36.199: The crown ether -crown-6 (structure on p. 372) has a strong aff...
Solutions for Chapter 8.7: ApplicAtions of solubility And solvAtion principles
Full solutions for Organic Chemistry | 6th Edition
Elements that have incompletely filled 5f subshells or readily give rise to cations that have incompletely filled 5f subshells. (7.9)
alpha (a) anomer
The cyclic hemiacetal of an aldose in which the hydroxyl group at the anomeric position is trans to the CH2OH
A steroid hormone, such as testosterone, that promotes tissue and muscle growth and development
In bond-line structures, agroup going behind the page.
In Diels-Alder reactions that produce bicyclic structures, the positions that are syn to the larger bridge.
Refers to a substance that rotates the plane of polarized light to the left.
A polymer that isformed via anionic polymerization.
Melt transition (Tm)
The temperature at which crystalline regions of a polymer melt.
A method for building a peptide from protected building blocks.
A chain comprised of a small number of amino acid residues.
The ratio of the actual (experimental) yield of a product to its theoretical (calculated) yield, multiplied by 100. (Section 3.7)
A form of lipid molecule that contains charged phosphate groups. (Section 24.9)
The emission of electrons from a metal surface induced by light. (Section 6.2)
Refers to two hydrogens bonded to a carbon atom. When a different atom replaces one or the other, the carbon becomes a chiral center. The hydrogens of the CH2 group of ethanol, for example, are prochiral. Replacing one of them by deuterium gives (R)-1-deuteroethanol; replacing the other gives (S)-1-deuteroethanol
The structure of a protein resulting from the clustering of several individual protein chains into a final specific shape. (Section 24.7)
Atomic orbitals that are achieved by mathematically averaging one s orbital with only one p orbital to form two hybridized atomic orbitals.
sp2 Hybrid orbital
A hybrid atomic orbital formed by the combination of one s atomic orbital and two 2p atomic orbitals.
The conjugate base of a thiol.
Vibrational infrared region
A common type of spin-spin coupling involving the H atoms on two C atoms that are bonded to each other.
Wavenumbers (—n )
The frequency of electromagnetic radiation expressed as the number of waves per centimeter, with units cm21 (read: reciprocal centimeters).