- 184.108.40.206: The d 1.21.5 region of the 300-MHz NMR spectrum of 1-chlorohexane, ...
- 220.127.116.11: Explain how the NMR spectra of (a) 3-methyl-2-buten-1-ol and (b) 1,...
Solutions for Chapter 13.6: using deuterium substitution in proton nmr
Full solutions for Organic Chemistry | 6th Edition
Hydrocarbons that contain one or more carbon-carbon double bonds. They have the general formula CnH2n, where n 5 2,3, . . . . (24.2)
A statement that the volume of a gas maintained at constant temperature and pressure is directly proportional to the number of moles of the gas. (Section 10.3)
An equilibrium property measured by the position of equilibrium in an acid-base reaction, as, for example, the acid-base reaction between ammonia and water.
The number of adjacent atoms to which an atom is directly bonded. In a complex the coordination number of the metal ion is the number of donor atoms to which it is bonded. (Sections 12.37 and 24.2)
The term used to express the concept of less shielding in NMR
A molecule with one end having a partial negative charge and the other end having a partial positive charge; a polar molecule. (Section 8.4)
The arrangement of electrons in the orbitals of an atom or molecule (Section 6.8)
The negative charge carried by an electron; it has a magnitude of 1.602 * 10-19 C. (Section 2.3)
A conformation that exhibits a gauche interaction.
The main fabricof cell membranes, assembled primarily fromphosphoglycerides.
melt transition temperature (Tm)
The temperature at which the crystallineregions of a polymer become amorphous.
The nucleophile in a Michael reaction.
A naturally occurring mixture of gaseous hydrocarbon compounds composed of hydrogen and carbon. (Section 5.8)
The very small, very dense, positively charged portion of an atom; it is composed of protons and neutrons. (Section 2.2)
The conjugate base of phenol or a substituted phenol.
Planck constant (h)
The constant that relates the energy and frequency of a photon, E = hn. Its value is 6.626 * 10-34 J@s. (Section 6.2)
A material that can be formed into particular shapes by application of heat and pressure. (Section 12.8)
A compound that contains a sulfur atom that has double bonds with two oxygen atoms and is flanked on both sides by R groups.
An ether(R!O!R) where the two R groups are notidentical.
van der Waals radius
The minimum distance of approach to an atom that does not cause nonbonded interaction strain.