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Solutions for Chapter 13.6: using deuterium substitution in proton nmr

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9781936221349

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Solutions for Chapter 13.6: using deuterium substitution in proton nmr

Solutions for Chapter 13.6
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This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry was written by and is associated to the ISBN: 9781936221349. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. Chapter 13.6: using deuterium substitution in proton nmr includes 2 full step-by-step solutions. Since 2 problems in chapter 13.6: using deuterium substitution in proton nmr have been answered, more than 39605 students have viewed full step-by-step solutions from this chapter.

Key Chemistry Terms and definitions covered in this textbook
  • alkenes.

    Hydrocarbons that contain one or more carbon-carbon double bonds. They have the general formula CnH2n, where n 5 2,3, . . . . (24.2)

  • Avogadro‚Äôs law

    A statement that the volume of a gas maintained at constant temperature and pressure is directly proportional to the number of moles of the gas. (Section 10.3)

  • Basicity

    An equilibrium property measured by the position of equilibrium in an acid-base reaction, as, for example, the acid-base reaction between ammonia and water.

  • coordination number

    The number of adjacent atoms to which an atom is directly bonded. In a complex the coordination number of the metal ion is the number of donor atoms to which it is bonded. (Sections 12.37 and 24.2)

  • Deshielding

    The term used to express the concept of less shielding in NMR

  • dipole

    A molecule with one end having a partial negative charge and the other end having a partial positive charge; a polar molecule. (Section 8.4)

  • electron configuration

    The arrangement of electrons in the orbitals of an atom or molecule (Section 6.8)

  • electronic charge

    The negative charge carried by an electron; it has a magnitude of 1.602 * 10-19 C. (Section 2.3)

  • gauche conformation

    A conformation that exhibits a gauche interaction.

  • lipid bilayer

    The main fabricof cell membranes, assembled primarily fromphosphoglycerides.

  • melt transition temperature (Tm)

    The temperature at which the crystallineregions of a polymer become amorphous.

  • Michael donor

    The nucleophile in a Michael reaction.

  • natural gas

    A naturally occurring mixture of gaseous hydrocarbon compounds composed of hydrogen and carbon. (Section 5.8)

  • nucleus

    The very small, very dense, positively charged portion of an atom; it is composed of protons and neutrons. (Section 2.2)

  • phenoxide

    The conjugate base of phenol or a substituted phenol.

  • Planck constant (h)

    The constant that relates the energy and frequency of a photon, E = hn. Its value is 6.626 * 10-34 J@s. (Section 6.2)

  • plastic

    A material that can be formed into particular shapes by application of heat and pressure. (Section 12.8)

  • sulfone

    A compound that contains a sulfur atom that has double bonds with two oxygen atoms and is flanked on both sides by R groups.

  • unsymmetrical ether

    An ether(R!O!R) where the two R groups are notidentical.

  • van der Waals radius

    The minimum distance of approach to an atom that does not cause nonbonded interaction strain.

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