- 220.127.116.11: Each of the following compounds protonates on nitrogen. Draw the co...
- 18.104.22.168: a) Ion A is more acidic than ion B in the gas phase. Is this the ac...
- 22.214.171.124: (a) Using the pKa values of the hydrocarbons and ammonia, estimate ...
- 126.96.36.199: Give the structures of the products in each of the following reacti...
- 188.8.131.52: Explain why graduate student Choke Fumely, in attempting to synthes...
- 184.108.40.206: Propose a synthesis of 4,4-dimethyl-2-pentyne (the compound in 14.1...
- 220.127.116.11: Outline two different preparations of 2-pentyne that involve an alk...
- 18.104.22.168: Propose another pair of reactants that could be used to prepare 2-h...
Solutions for Chapter 14.7: Acidity of 1-Alkynes
Full solutions for Organic Chemistry | 6th Edition
The product obtained when the aldehyde group of an aldose is reduced.
The product formed when the C"O group of a monosaccharide is reduced to a CHOH group.
The product formed when the !CHO group of an aldose is oxidized to a !COOH group
A hydrocarbon that lacks p bonds.
Compounds of carbon and hydrogen containing only carbon–carbon single bonds. (Sections 2.9 and 24.2)
An SR group.
A steroid hormone, such as testosterone, that mediates the development of sexual characteristics of males.
A solvent that cannot serve as a hydrogen-bond donor; nowhere in the molecule is there a hydrogen bonded to an atom of high electronegativity. Common aprotic solvents are dichloromethane, diethyl ether, and dimethyl sulfoxide
An estimate of the size of an atom. See bonding atomic radius. (Section 7.3)
The heating of an ore to bring about its decomposition and the elimination of a volatile product. For example, a carbonate ore might be calcined to drive off CO2. (Section 23.2)
A polydentate ligand that is capable of occupying two or more sites in the coordination sphere. (Section 23.3)
A bond that results when two atoms share a pair of electrons.
An element that forms two bonds, such as oxygen.
A state that is achieved when a compound absorbs energy.
A chemical combination of two or more atoms. (Sections 1.1 and 2.6)
The negative log in base 10 of the aquated hydrogen ion concentration: pH = -log3H+4. (Section 16.4)
A detailed picture, or model, of how the reaction occurs; that is, the order in which bonds are broken and formed and the changes in relative positions of the atoms as the reaction proceeds. (Section 14.6)
second law of thermodynamics
A statement of our experience that there is a direction to the way events occur in nature. When a process occurs spontaneously in one direction, it is nonspontaneous in the reverse direction. It is possible to state the second law in many different forms, but they all relate back to the same idea about spontaneity. One of the most common statements found in chemical contexts is that in any spontaneous process the entropy of the universe increases. (Section 19.2)
standard emf, also called the standard cell potential 1E°2
The emf of a cell when all reagents are at standard conditions. (Section 20.4)
A polymer with alternating R and S confi gurations at the chiral centers along its chain, as, for example, syndiotactic polypropylene