Solutions for Chapter 18: THE CHEmisTRy of ARyl HAlidEs, VinyliC HAlidEs, And PHEnols. TRAnsiTion-mETAl CATAlysis

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9781936221349

Organic Chemistry | 6th Edition | ISBN: 9781936221349 | Authors: Marc Loudon, Jim Parise

Solutions for Chapter 18: THE CHEmisTRy of ARyl HAlidEs, VinyliC HAlidEs, And PHEnols. TRAnsiTion-mETAl CATAlysis

Solutions for Chapter 18
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Textbook: Organic Chemistry
Edition: 6
Author: Marc Loudon, Jim Parise
ISBN: 9781936221349

Since 47 problems in chapter 18: THE CHEmisTRy of ARyl HAlidEs, VinyliC HAlidEs, And PHEnols. TRAnsiTion-mETAl CATAlysis have been answered, more than 16033 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. Chapter 18: THE CHEmisTRy of ARyl HAlidEs, VinyliC HAlidEs, And PHEnols. TRAnsiTion-mETAl CATAlysis includes 47 full step-by-step solutions. Organic Chemistry was written by and is associated to the ISBN: 9781936221349. This expansive textbook survival guide covers the following chapters and their solutions.

Key Chemistry Terms and definitions covered in this textbook
  • acid-dissociation constant (Ka)

    An equilibrium constant that expresses the extent to which an acid transfers a proton to solvent water. (Section 16.6)

  • auxochrome

    When applying Woodward-Fieser rules, the groups attached to the chromophore.

  • beta sheet

    A structural form of protein in which two strands of amino acids are hydrogen-bonded together in a zipperlike configuration. (Section 24.7)

  • Brønsted-Lowry acid

    A compound that can serve as a proton donor.

  • complex ion (complex)

    An assembly of a metal ion and the Lewis bases (ligands) bonded to it. (Section 17.5)

  • Confi gurational isomers

    Isomers that differ by the confi guration of substituents on an atom. Refers to the arrangement of atoms about a stereocenter

  • diazonium salt

    An ionic compound that is formed upon treatment of a primary amine with NaNO2 and HCl.

  • E1

    A unimolecular elimination reaction.

  • Edman degradatio

    A method for selectively cleaving and identifying the N-terminal amino acid of a polypeptide chain.

  • electron affinity

    The energy change that occurs when an electron is added to a gaseous atom or ion. (Section 7.5)

  • Fischer esterification

    A process in which a carboxylic acid is converted into an ester when treated with an alcohol in the presence of an acid catalyst.

  • hydrocracking

    A process performed in the presence of hydrogen gas by which large alkanes in petroleum are converted into smaller alkanes that are more suitable for use as gasoline.

  • intermediate

    A structure corresponding to a local minimum (valley) in an energy diagram.

  • Levorotatory

    Refers to a substance that rotates the plane of polarized light to the left.

  • molecular solids

    Solids that are composed of molecules. (Sections 12.1 and 12.6)

  • Nucleophile

    From the Greek meaning nucleus-loving. Any species that can donate a pair of electrons to form a new covalent bond; alternatively, a Lewis base

  • oxidation

    A reaction in which one compound undergoes an increase in oxidation state.

  • Primary structure of proteins

    The sequence of amino acids in the polypeptide chain, read from the N-terminal amino acid to the C-terminal amino acid.

  • solubility-product constant (solubility product)1Ksp2

    An equilibrium constant related to the equilibrium between a solid salt and its ions in solution. It provides a quantitative measure of the solubility of a slightly soluble salt. (Section 17.4)

  • Specifi c rotation

    The observed rotation of the plane of polarized light when a sample is placed in a tube 1.0 dm in length and at a concentration of 1 g/mL for a solution. For a pure liquid, concentration is expressed in g/mL (density).

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