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- 184.108.40.206: Suggest a structure for the acetal product of each reaction. (a) (b)
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Solutions for Chapter 19.1: NomeNclature of aldehydes aNd KetoNes
Full solutions for Organic Chemistry | 6th Edition
As protons are added one by one to the nucleus to build up the elements, electrons similarly are added to the atomic orbitals. (7.9)
An elementary step that involves two molecules. (13.5)
The generally larger formation constants for polydentate ligands as compared with the corresponding monodentate ligands. (Section 23.3)
A polymer,that is formed via a condensation reaction.
A bond that results when two atoms share a pair of electrons.
A compound containing a double bond (consisting of one or two C, N, or O atoms) that can react with a conjugated diene to give a Diels-Alder adduct.
In the VSEPR model, a region about a central atom in which an electron pair is concentrated. (Section 9.2)
Lanthanide and actinide elements in which the 4f or 5f orbitals are partially occupied. (Section 6.9)
The splitting of a large nucleus into two smaller ones. (Section 21.6)
Glass transition temperature (TG)
The temperature at which a polymer undergoes the transition from a hard glass to a rubbery state
A law stating that the concentration of a gas in a solution, Sg, is proportional to the pressure of gas over the solution: Sg = kPg. (Section 13.3)
Cleavage of a single bond by H2, most commonly accomplished by treating a compound with H2 in the presence of a transition metal catalyst.
When signal splitting occurs in 1H NMR spectroscopy, the distance (in hertz) between the individual peaks of a signal.
localized lone pair
A lone pair thatis not participating in resonance.
The state of a system at a particular instant; one of many possible energetically equivalent ways to arrange the components of a system to achieve a particular state. (Section 19.3)
quaternary ammonium salt
An ionic compound containing a positively charged nitrogen atom connected to four alkyl groups.
sigma (s) bond
A bond that is characterized by circular symmetry with respect to the bond axis.
An interaction in which nuclear spins of adjacent atoms infl uence each other and lead to the spitting of NMR signals.
three-center, two-electron bonds
A bond in which two electrons are associated with three atoms, such as in diborane (B2H6).
In NMR spectroscopy, a signal that is comprised of three peaks.