- 19.1.19.1: Give the structure for each of the following compounds. (a) isobutr...
- 19.1.19.25: Propose syntheses of each of the following acetals from carbonyl co...
- 19.1.19.2: Give the substitutive name for each of the following compounds. (a)...
- 19.1.19.26: Suggest a structure for the acetal product of each reaction. (a) (b)
- 19.1.19.27: Outline a synthesis of the following compound from p-bromoacetophen...
- 19.1.19.28: Draw the structure of (a) the oxime of acetone; (b) the imine forme...
Solutions for Chapter 19.1: NomeNclature of aldehydes aNd KetoNes
Full solutions for Organic Chemistry | 6th Edition
ISBN: 9781936221349
This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. Organic Chemistry was written by and is associated to the ISBN: 9781936221349. Since 6 problems in chapter 19.1: NomeNclature of aldehydes aNd KetoNes have been answered, more than 16011 students have viewed full step-by-step solutions from this chapter. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 19.1: NomeNclature of aldehydes aNd KetoNes includes 6 full step-by-step solutions.
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Aufbau principle.
As protons are added one by one to the nucleus to build up the elements, electrons similarly are added to the atomic orbitals. (7.9)
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bimolecular reaction.
An elementary step that involves two molecules. (13.5)
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chelate effect
The generally larger formation constants for polydentate ligands as compared with the corresponding monodentate ligands. (Section 23.3)
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condensation polymer
A polymer,that is formed via a condensation reaction.
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covalent bond
A bond that results when two atoms share a pair of electrons.
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Dienophile
A compound containing a double bond (consisting of one or two C, N, or O atoms) that can react with a conjugated diene to give a Diels-Alder adduct.
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electron domain
In the VSEPR model, a region about a central atom in which an electron pair is concentrated. (Section 9.2)
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f-block metals
Lanthanide and actinide elements in which the 4f or 5f orbitals are partially occupied. (Section 6.9)
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fission
The splitting of a large nucleus into two smaller ones. (Section 21.6)
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Glass transition temperature (TG)
The temperature at which a polymer undergoes the transition from a hard glass to a rubbery state
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Henry’s law
A law stating that the concentration of a gas in a solution, Sg, is proportional to the pressure of gas over the solution: Sg = kPg. (Section 13.3)
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Hydrogenolysis
Cleavage of a single bond by H2, most commonly accomplished by treating a compound with H2 in the presence of a transition metal catalyst.
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J value
When signal splitting occurs in 1H NMR spectroscopy, the distance (in hertz) between the individual peaks of a signal.
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localized lone pair
A lone pair thatis not participating in resonance.
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microstate
The state of a system at a particular instant; one of many possible energetically equivalent ways to arrange the components of a system to achieve a particular state. (Section 19.3)
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quaternary ammonium salt
An ionic compound containing a positively charged nitrogen atom connected to four alkyl groups.
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sigma (s) bond
A bond that is characterized by circular symmetry with respect to the bond axis.
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Spin-spin coupling
An interaction in which nuclear spins of adjacent atoms infl uence each other and lead to the spitting of NMR signals.
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three-center, two-electron bonds
A bond in which two electrons are associated with three atoms, such as in diborane (B2H6).
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triplet
In NMR spectroscopy, a signal that is comprised of three peaks.