- 2.3.9: Draw the conjugate acid of each of the following: a. CH3CH2OH b. CH...
- 2.3.10: a. Write an equation showing CH 3 OH reacting as an acid with NH 3 ...
- 2.3.11: Estimate the p Ka values of the following compounds: CH3CH2CH2NH2 C...
- 2.3.12: a. Which is a stronger base, CH3COO- or HCOO- ? (The p Ka of CH 3 C...
- 2.3.13: Using the p Ka values in Section 2.3 , rank the following species i...
Solutions for Chapter 2.3: Organic Acids and Bases
Full solutions for Organic Chemistry | 7th Edition
Element in which the 5f orbitals are only partially occupied. (Section 6.8)
An atom or group of atoms bearing a negative charge.
An amine in which nitrogen is bonded to one or more aryl groups.
conjugate acid-base pair.
An acid and its conjugate base or a base and its conjugate acid. (15.1)
The deterioration of metals by an electrochemical process. (18.7)
An ArN2 1 or RN2 1 ion
The escape of a gas through an orifice or hole. (Section 10.8)
A solute that produces ions in solution; an electrolytic solution conducts an electric current. (Section 4.1)
electron impact ionization (EI)
In mass spectrometry, an ionization technique that involves bombarding a compoundwith high-energy electrons.
A reaction in which a carboxylic acid undergoes a-halogenation when treated with bromine in the presence of PBr3.
A monosaccharide containing a ketone group.
Experimental conditions under which the composition of the product mixture is determined by the relative rates of formation of each product.
Part per million (ppm)
Units used on NMR spectra to record chemical shift relative to the TMS standard.
A compound with a weak bond that undergoes homolytic bond cleavage with great ease, producing radicals that can initiate a radical chain process.
A test for determining the relationship between two protons. The compound is drawn two times, each time replacing one of the protons with deuterium. If the two compounds are identical, the protons are homotopic. If the two compounds are enantiomers, the protons are enantiotopic. If the two compounds are diastereomers, the protons are diastereotopic.
A term used to indicate that a certain volume of a compound will dissolve in a specified amount of a liquid at room temperature.
A conformation in which nearby groups in a Newman projection have a dihedral angle of 60°.
The addition of atoms or groups of atoms to the same face of a carbon-carbon double bond.
A solution to a set of equations that defi nes the energy of an electron in an atom and the region of space it may occupy.
The distance between consecutive peaks on a wave