Solutions for Chapter 4.16: Nitrogen and Phosphorus Atoms Can Be Asymmetric Centers
Full solutions for Organic Chemistry | 7th Edition
Solutions for Chapter 4.16: Nitrogen and Phosphorus Atoms Can Be Asymmetric CentersGet Full Solutions
A compound that possesses a hydroxyl group (OH).
The compound CH2"C"CH2. Any compound that contains adjacent carbon-carbon double bonds; that is, any molecule that contains a C"C"C functional group.
Next to a carbon-carbon double bond.
An equilibrium property measured by the position of equilibrium in an acid-base reaction, as, for example, the acid-base reaction between ammonia and water.
chemical shift (d)
In an NMR spectrum, the location of a signal, defined relative to the frequency of absorption of a reference compound, tetramethylsilane (TMS).
In gas chromatography, a plot that identifies the retention time of each compound in the mixture.
A technique by which compounds are separated from each other based on a difference in the way they interact with the medium (the adsorbent) through which they are passed.
A polymerization in which chain growth occurs in a stepwise manner between difunctional monomers. Also called step-growth polymerization.
Alkanes whose carbon atoms are joined in rings. (24.2)
A molecule with one end having a partial negative charge and the other end having a partial positive charge; a polar molecule. (Section 8.4)
dipole moment (m)
The amount of partial charge (d ) on either end of a dipole multiplied by the distance of separation (d): m=d × d
A group derived by removing an H from benzene; abbreviated C6H5! or Ph!.
pi (p) bond
A bond formed from adjacent, overlapping p orbitals.
Polymers that are similar in structure to polyesters but with repeating carbonate groups (!O!CO2!) instead of repeating ester groups (!CO2!). polycyclic aromatic hydrocarbons
A material that has electrical conductivity between that of a metal and that of an insulator. (Section 12.7)
A selective reducing agent (NaBH3CN) that can be used for reductive amination.
A conformation in which nearby groups in a Newman projection have a dihedral angle of 60°.
A plant or animal lipid having the characteristic tetracyclic ring structure of the steroid nucleus, namely three sixmembered rings and one fi ve-membered ring.
A compound that contains a sulfur atom that has double bonds with two oxygen atoms and is flanked on both sides by R groups.
A rule stating that the major product of a b-elimination reaction is the most stable alkene; that is, it is the alkene with the greatest number of substituents on the carboncarbon double bond