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Solutions for Chapter 4.16: Nitrogen and Phosphorus Atoms Can Be Asymmetric Centers

Organic Chemistry | 7th Edition | ISBN: 9780321803221 | Authors: Paula Yurkanis Bruice

Full solutions for Organic Chemistry | 7th Edition

ISBN: 9780321803221

Organic Chemistry | 7th Edition | ISBN: 9780321803221 | Authors: Paula Yurkanis Bruice

Solutions for Chapter 4.16: Nitrogen and Phosphorus Atoms Can Be Asymmetric Centers

Solutions for Chapter 4.16
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Organic Chemistry was written by and is associated to the ISBN: 9780321803221. This expansive textbook survival guide covers the following chapters and their solutions. Since 1 problems in chapter 4.16: Nitrogen and Phosphorus Atoms Can Be Asymmetric Centers have been answered, more than 35351 students have viewed full step-by-step solutions from this chapter. Chapter 4.16: Nitrogen and Phosphorus Atoms Can Be Asymmetric Centers includes 1 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7.

Key Chemistry Terms and definitions covered in this textbook
  • alcohol

    A compound that possesses a hydroxyl group (OH).

  • Allene

    The compound CH2"C"CH2. Any compound that contains adjacent carbon-carbon double bonds; that is, any molecule that contains a C"C"C functional group.

  • Allylic

    Next to a carbon-carbon double bond.

  • Basicity

    An equilibrium property measured by the position of equilibrium in an acid-base reaction, as, for example, the acid-base reaction between ammonia and water.

  • chemical shift (d)

    In an NMR spectrum, the location of a signal, defined relative to the frequency of absorption of a reference compound, tetramethylsilane (TMS).

  • chromatogram

    In gas chromatography, a plot that identifies the retention time of each compound in the mixture.

  • column chromatography

    A technique by which compounds are separated from each other based on a difference in the way they interact with the medium (the adsorbent) through which they are passed.

  • Condensation polymerization

    A polymerization in which chain growth occurs in a stepwise manner between difunctional monomers. Also called step-growth polymerization.

  • cycloalkanes.

    Alkanes whose carbon atoms are joined in rings. (24.2)

  • dipole

    A molecule with one end having a partial negative charge and the other end having a partial positive charge; a polar molecule. (Section 8.4)

  • dipole moment (m)

    The amount of partial charge (d ) on either end of a dipole multiplied by the distance of separation (d): m=d × d

  • Phenyl group

    A group derived by removing an H from benzene; abbreviated C6H5! or Ph!.

  • pi (p) bond

    A bond formed from adjacent, overlapping p orbitals.

  • polycarbonates

    Polymers that are similar in structure to polyesters but with repeating carbonate groups (!O!CO2!) instead of repeating ester groups (!CO2!). polycyclic aromatic hydrocarbons

  • semiconductor

    A material that has electrical conductivity between that of a metal and that of an insulator. (Section 12.7)

  • sodium cyanoborohydride

    A selective reducing agent (NaBH3CN) that can be used for reductive amination.

  • staggered conformation

    A conformation in which nearby groups in a Newman projection have a dihedral angle of 60°.

  • Steroid

    A plant or animal lipid having the characteristic tetracyclic ring structure of the steroid nucleus, namely three sixmembered rings and one fi ve-membered ring.

  • sulfone

    A compound that contains a sulfur atom that has double bonds with two oxygen atoms and is flanked on both sides by R groups.

  • Zaitsev’s rule

    A rule stating that the major product of a b-elimination reaction is the most stable alkene; that is, it is the alkene with the greatest number of substituents on the carboncarbon double bond

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