- 6.12.33: Identify each of the following reactions as an oxidation reaction, ...
- 6.12.34: What alkene would you start with if you wanted to synthesize a. pen...
- 6.12.35: How many different alkenes can be hydrogenated to form a. butane? b...
Solutions for Chapter 6.12: The Addition of Hydrogen to an Alkene
Full solutions for Organic Chemistry | 7th Edition
(n 1 1) rule
If a hydrogen has n hydrogens nonequivalent to it but equivalent among themselves on the same or adjacent atom(s), its 1 H!NMR signal is split into (n 1 1) peaks
A group that is formed by removing a hydrogen atom from an alkane. (Section 25.3)
atomic number (Z).
The number of protons in the nucleus of an atom. (2.3)
A structure containing two rings that are fused together.
The angles made by the lines joining the nuclei of the atoms in a molecule. (Section 9.1)
A means of protecting a metal against corrosion by making it the cathode in a voltaic cell. This can be achieved by attaching a more easily oxidized metal, which serves as an anode, to the metal to be protected. (Section 20.8)
A drawing style in which none of the bonds are drawn. Groups of atoms are clustered together when possible. For example, isopropanol has two CH3 groups, both of which are connected to the central carbon atom, shown like this: (CH3)2CHOH.
crystalline solid (crystal)
A solid whose internal arrangement of atoms, molecules, or ions possesses a regularly repeating pattern in any direction through the solid. (Section 12.2)
Compounds containing the CN2 ion. (22.3)
Dalton’s law of partial pressures
A law stating that the total pressure of a mixture of gases is the sum of the pressures that each gas would exert if it were present alone. (Section 10.6)
Diamagnetic current in NMR
The circulation of electron density in a molecule in an applied magnetic fi eld.
An ArN2 1 or RN2 1 ion
Theresulting net attraction between two dipoles.
A charge associated with any atom that does not exhibit the appropriate number of valence electrons.
A characteristic group of atoms/bonds that possess a predictable chemical behavior.
A compound of the type CHX3 where X is a halogen.
A complex whose electrons populate the d orbitals to give the maximum number of unpaired electrons. (Section 23.6)
A reaction that involves the participation of ions as reactants, intermediates, or products.
A radioisotope that can be used to trace the path of an element in a chemical system. (Section 21.5)
A compound that is similar in structure to an ether, but the oxygen atom has been replaced with a sulfur atom. Also called a thioether.