- 11.4.12: Draw the major product obtained when each of the following alcohols...
- 11.4.13: Heating an alcohol with sulfuric acid is a good way to prepare a sy...
- 11.4.11: Explain why benzyl bromide and allyl bromide cannot undergo either ...
- 11.4.14: Propose a mechanism for each of the following reactions: a. H2SO4 C...
- 11.4.15: Draw the product of each of the following reactions: a. OH + HBr CH...
- 11.4.16: Explain why the following alcohols, when heated with acid, form the...
- 11.4.17: What stereoisomers are formed in the following reactions? Which ste...
- 11.4.18: Suppose the following compound is heated in the presence of H 2 SO ...
- 11.4.19: What alcohol would you treat with phosphorus oxychloride and pyridi...
Solutions for Chapter 11.4: E2 and E1 Reactions Are Stereoselective
Full solutions for Organic Chemistry | 7th Edition
An unsaturated hydrocarbon that contains one or more carbon-carbon triple bonds.
An equation that relates the rate constant for a reaction to the frequency factor, A, the activation energy, Ea, and the temperature, T: k = Ae-Ea>RT. In its logarithmic form it is written ln k = -Ea>RT + ln A. (Section 14.5)
A polydentate ligand that is capable of occupying two or more sites in the coordination sphere. (Section 23.3)
Compounds containing the CN2 ion. (22.3)
A molecule containing an !S!S! group
Fischer esterifi cation
The process of forming an ester by refl uxing a carboxylic acid and an alcohol in the presence of an acid catalyst, commonly H2SO4, ArSO3H, or HCl
An atom or group of atoms that imparts characteristic chemical properties to an organic compound. (Section 24.1)
An organic compound containing at least one halogen.
Compounds formed between two different halogen elements. Examples include IBr and BrF3. (Section 22.4)
A set of assumptions about the nature of gases. These assumptions, when translated into mathematical form, yield the ideal-gas equation. (Section 10.7)
A spherical arrangement of organic molecules in water solution clustered so that their hydrophobic parts are buried inside the sphere and their hydrophilic parts are on the surface of the sphere and in contact with water
During the polymerization process, compounds constructed from just a few monomers.
A solvent that is a hydrogen-bond donor. Common protic solvents are water, low-molecular-weight alcohols, and low-molecular weight carboxylic acids.
A process in which heat converts a mineral in an ore from one chemical form to another and eventually to the free metal. (Section 23.2)
The arrangement of polypeptide monomers into a noncovalently bonded aggregate.
A reaction in which a compound undergoes a decrease in oxidation state.
A bimolecular nucleophilic substitution reaction.
A reaction in which an atom or group of atoms in a compound is replaced by another atom or group of atoms.
A reaction that has a rate equation in which the sum of all exponents is three
A double-helix model for the secondary structure of a DNA molecule