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Solutions for Chapter 11: Reactions of Alcohols, Ethers, Amines, Thiols, and Thioethers

Organic Chemistry | 7th Edition | ISBN: 9780321803221 | Authors: Paula Yurkanis Bruice

Full solutions for Organic Chemistry | 7th Edition

ISBN: 9780321803221

Organic Chemistry | 7th Edition | ISBN: 9780321803221 | Authors: Paula Yurkanis Bruice

Solutions for Chapter 11: Reactions of Alcohols, Ethers, Amines, Thiols, and Thioethers

Solutions for Chapter 11
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Textbook: Organic Chemistry
Edition: 7
Author: Paula Yurkanis Bruice
ISBN: 9780321803221

Chapter 11: Reactions of Alcohols, Ethers, Amines, Thiols, and Thioethers includes 42 full step-by-step solutions. Organic Chemistry was written by and is associated to the ISBN: 9780321803221. Since 42 problems in chapter 11: Reactions of Alcohols, Ethers, Amines, Thiols, and Thioethers have been answered, more than 35447 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7. This expansive textbook survival guide covers the following chapters and their solutions.

Key Chemistry Terms and definitions covered in this textbook
  • Alkyl group

    A group derived by removing a hydrogen from an alkane; given the symbol R!

  • Allene

    The compound CH2"C"CH2. Any compound that contains adjacent carbon-carbon double bonds; that is, any molecule that contains a C"C"C functional group.

  • base

    A substance that is an H+ acceptor; a base produces an excess of OH-1aq2 ions when it dissolves in water. (Section 4.3)

  • configuration

    The 3D spatial orientation of the groups connected to a chirality center (R or S ) or of the groups in a stereoisiomeric alkene (E or Z).

  • Conjugate addition

    Addition of a nucleophile to the b-carbon of an a,b-unsaturated carbonyl compound. (Section 20.2A) Addition to carbons 1 and 4 of a conjugated diene.

  • covalent bond

    A bond that results when two atoms share a pair of electrons.

  • critical pressure (Pc).

    The minimum pressure necessary to bring about liquefaction at the critical temperature. (11.8)

  • diastereotopic

    Nonequivalent protons for which the replacement test produces diastereomers.

  • Disulfide

    A molecule containing an !S!S! group

  • Enantioselective reaction

    A reaction that produces one enantiomer in preference to the other.

  • epoxide

    A cyclic ether containing a three-membered ring system. Also called an oxirane (also see Sect. 14.7).

  • ether

    A compound with the structure R!O!R.

  • hard water

    Water that contains appreciable concentrations of Ca2 + and Mg 2 + ; these ions react with soaps to form an insoluble material. (Section 18.4)

  • ignal splitting in NMR

    Spin-spin coupling with adjacent nuclei split NMR signals depending on the extent of coupling and the number of adjacent equivalent nuclei.

  • mixture

    A combination of two or more substances in which each substance retains its own chemical identity. (Section 1.2)

  • oxonium ion

    An intermediate with a positively charged oxygen atom.

  • oxymercuration-demercuration

    A two-step process for the Markovnikov addition of water across an alkene. With this process, carbocation rearrangements do not occur.

  • Pi (p) molecular orbital

    A molecular orbital formed by overlapping parallel 2p orbitals on adjacent atoms; its electron density lies above and below the line connecting the atoms

  • R (Section 3.3)

    From the Latin, rectus, straight, correct; used in the R,S convention to show that the order of priority of groups on a chiral center is clockwise.

  • Valence shell

    The outermost occupied electron shell of an atom.

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