- 13.8.14: a. What hydrocarbon with molecular formula C 4 H 10 forms only two ...
- 13.8.15: Draw the stereoisomers of the major monobromination products obtain...
Solutions for Chapter 13.8: The Stereochemistry of Radical Substitution and Radical Addition Reactions
Full solutions for Organic Chemistry | 7th Edition
Solutions for Chapter 13.8: The Stereochemistry of Radical Substitution and Radical Addition ReactionsGet Full Solutions
Polymerization that occurs through coupling of monomers with one another, with no other products formed in the reaction. (Section 12.8)
A reaction in which a reagent adds to the two carbon atoms of a carbon–carbon multiple bond. (Section 24.3)
Compounds with a carbonyl functional group and the general formula RCHO, where R is an H atom, an alkyl, or an aromatic group. (24.4)
The product obtained when the aldehyde group of an aldose is reduced.
A !CH2CH"CH2 group.
A hydrocarbon that contains one or more benzene rings. (24.1)
A reaction in which the Gibbs free energy of the products is lower than that of the reactants. The position of equilibrium for an exergonic reaction favors products.
A fi ve-membered cyclic form of a monosaccharide.
The SI unit for radiation dose
Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions
The mixing of different types of atomic orbitals to produce a set of equivalent hybrid orbitals. (Section 9.5)
The energy required to remove an electron from a gaseous atom when the atom is in its ground state. (Section 7.4)
The absolute temperature scale; the SI unit for temperature is the kelvin. Zero on the Kelvin scale corresponds to -273.15 °C. (Section 1.4)
A process by which the chain of a carbohydrate is lengthened by one carbon atom.
In the addition of HX, H2O, or ROH to an alkene, hydrogen adds to the carbon of the double bond having the greater number of hydrogens.
N-Terminal amino acid
The amino acid at the end of a polypeptide chain having the free !NH2 group
The energy that an object possesses as a result of its composition or its position with respect to another object. (Section 5.1)
The digits that indicate the precision with which a measurement is made; all digits of a measured quantity are significant, including the last digit, which is uncertain. (Section 1.5)
A protein used to transport molecules or ions from one location to another. Hemoglobin is a classic example of a transport protein, used to transport molecular oxygen from the lungs to all the tissues of the body.
A signal of an NMR spectrum that is shifted toward the right (smaller chemical shift) on the chart paper.