Solutions for Chapter 14.13: THE POSITION OF ABSORPTION BANDS
Full solutions for Organic Chemistry | 7th Edition
An amino acid in which the amino group is on the carbon adjacent to the carboxyl group.
A carbon atom that is immediately adjacent to a benzene ring.
A thermodynamic cycle based on Hess’s law that relates the lattice energy of an ionic substance to its enthalpy of formation and to other measurable quantities. (Section 8.2)
Phosphoglycerides that contain ethanolamine.
A step in a chain reaction characterized by the formation of reactive intermediates (radicals, anions, or cations) from nonradical or noncharged molecules
A polymer that is constructed from more than one repeating unit.
A bond in which two electrons are shared by two atoms. (9.4)
Lanthanide and actinide elements in which the 4f or 5f orbitals are partially occupied. (Section 6.9)
Any b-elimination that occurs preferentially to give the less substituted alkene as the major product.
An ion formed by the addition of an electron to a hydrogen atom: H-. (Section 7.7)
nuclear magnetic resonance (NMR)
A form of spectroscopy that involves the study of the interaction between electromagnetic radiation and the nuclei of atoms.
Replacing this hydrogen by deuterium gives a chiral center with an S confi guration
A nonprotein unit attached to a protein, such as heme in hemoglobin.
Having specifi c values for energy and momentum
A vibrational molecular spectroscopy that is complementary to infrared (IR) spectroscopy in that infrared inactive vibrations are seen in Raman spectroscopy.
A starting substance in a chemical reaction; it appears to the left of the arrow in a chemical equation. (Section 3.1)
A process that can go back and forth between states along exactly the same path; a system at equilibrium is reversible if equilibrium can be shifted by an infinitesimal modification of a variable such as temperature. (Section 19.1)
A unimolecular nucleophilic substitution reaction.
A geometry adopted by an atom that has one lone pair and a steric number of 4.
Williamson ether synthesis
A general method for the synthesis of dialkyl ethers by an SN2 reaction between a haloalkane and an alkoxide ion.
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