- 15.2.40: Answer the following questions for each of the following compounds:...
- 15.2.41: Describe the proton-coupled 13 C NMR spectra for compounds 1, 3, an...
- 15.2.42: How can 1,2-, 1,3-, and 1,4-dinitrobenzene be distinguished by a. 1...
- 15.2.43: Identify each compound in Figure 15.37 from its molecular formula a...
Solutions for Chapter 15.2: 13C NMR Spectroscopy
Full solutions for Organic Chemistry | 7th Edition
An elementary step that involves two molecules. (13.5)
A cyclic polyether derived from ethylene glycol and substituted ethylene glycols.
A type of magnetism that causes a substance with no unpaired electrons to be weakly repelled from a magnetic field. (Section 9.8)
An ionic compound that is formed upon treatment of a primary amine with NaNO2 and HCl.
Carbohydrates comprisedof two monosaccharide units joined via aglycosidic linkage between the anomeric carbonof one monosaccharide and a hydroxyl group ofthe other monosaccharide.
The escape of a gas through an orifice or hole. (Section 10.8)
The SI unit for radiation dose
A vacancy in the valence band of a semiconductor, created by doping. (Section 12.7)
A type of carbocation rearrangement that involves the migration of a hydride ion (H-).
A reaction with water. When a cation or anion reacts with water, it changes the pH. (Sections 16.9 and 24.4)
Infrared (IR) spectroscopy
A spectroscopic technique in which a compound is irradiated with infrared radiation, absorption of which causes covalent bonds to change from a lower vibration state to a higher one. Infrared spectroscopy is particularly valuable for determining the kinds of functional groups present in a molecule.
A bond between oppositely charged ions. The ions are formed from atoms by transfer of one or more electrons. (Section 8.1)
A spherical arrangement of organic molecules in water solution clustered so that their hydrophobic parts are buried inside the sphere and their hydrophilic parts are on the surface of the sphere and in contact with water
Radiation that does not have sufficient energy to remove an electron from a molecule. (Section 21.9)
Compounds that are very similar in structure to triglycerides, with the main difference being that one of the three fatty acid residues is replaced by a phosphoester group.
Light for which all photons have the same polarization, generally formed by passing light through a polarizing filter.
A name that is assigned using the rules of IUPAC nomenclature.
A polymer that can be melted and molded into a shape that is retained when it is cooled.
The highest energy point on a reaction coordinate diagram. The chemical structure at this point is commonly called an activated complex.
van der Waals radius
The minimum distance of approach to an atom that does not cause nonbonded interaction strain.