- 17.9.25: What reducing agents should be used to obtain the desired target mo...
- 17.9.26: Explain why carbonnitrogen double bonds and carbonnitrogen triple b...
- 17.9.27: What are the products of the following reactions? a. 1. NaBH4 2. H2...
Solutions for Chapter 17.9: CHEMOSELECTIVE REACTIONS
Full solutions for Organic Chemistry | 7th Edition
Elements that have incompletely filled 5f subshells or readily give rise to cations that have incompletely filled 5f subshells. (7.9)
The product obtained when the aldehyde group of an aldose is oxidized.
A bond that results when two atoms share a pair of electrons.
For alkenes, a stereodescriptorthat indicates that the two priority groups are on opposite sides of the p bond.
electron impact ionization (EI)
In mass spectrometry, an ionization technique that involves bombarding a compoundwith high-energy electrons.
A technique for separating amino acids from each other based on a difference in pI values.
Haloalkene (vinylic halide)
A compound containing a halogen atom bonded to one of the carbons of a carbon-carbon double bond.
A cyclic compound whose ring contains more than one kind of atom. Oxirane (ethylene oxide), for example, is a heterocycle whose ring contains two carbon atoms and one oxygen atom.
The highest occupied molecular orbital.
A polymer in which the repeating units contain chirality centers which all have the same configuration.
A compound in which the carbonyl group 1C “O2 occurs at the interior of a carbon chain and is therefore flanked by carbon atoms. (Section 24.4)
A CH2 group.
A carbohydrate that cannot be hydrolyzed to a simpler carbohydrate.
A reagent used for allylic bromination to avoid a competing reaction in which bromine adds across the p bond.
parts per million (ppm)
The concentration of a solution in grams of solute per 106 (million) grams of solution; equals milligrams of solute per liter of solution for aqueous solutions. (Section 13.4)
Polypeptide chains comprised of more than 40 or 50 amino acids.
A reaction that has a rate equation in which the sum of all exponents is two.
Isomers that have the same molecular formula and the same connectivity of their atoms but a different orientation of their atoms in space
High-molecular-weight esters that are constructed from carboxylic acids and alcohols.
Rules for predicting the wavelength of maximum absorption for a compound with extended conjugation.