- 6.5.9: The pKa of a protonated alcohol is about -2.5, and the pKa of an al...
- 6.5.10: Answer the following questions about the mechanism for the acid-cat...
- 6.5.11: PROBLEM 11 What is the major product obtained from the acid-catalyz...
Solutions for Chapter 6.5: The Addition of Water to an Alkene
Full solutions for Organic Chemistry | 8th Edition
A list of metals in order of decreasing ease of oxidation. (Section 4.4)
A high-energy molecular orbital resulting from the destructive interference between atomic orbitals.
An acid that is not a proton donor; an acid that is an electron pair acceptor in a Lewis acid-base reaction.
A binary compound of carbon with a metal or metalloid. (Section 22.9)
A [3,3] sigmatropic rearrangement that is observed for allylic vinylic ethers.
A chemical reaction that proceeds with evolution of heat and usually also a flame; most combustion involves reaction with oxygen, as in the burning of a match. (Section 3.2)
A carbohydrate containing two monosaccharide units joined by a glycosidic bond.
A termination process that involves the abstraction of a hydrogen atom from the beta position of the propagating radical of one chain by the radical endgroup of another chain.
E (Section 5.2C)
From the German, entgegen, opposite. Specifi es that groups of higher priority on the carbons of a double bond are on opposite sides
In Diels-Alder reactions that produce bicyclic structures, the positions that are syn to the larger bridge.
A protein molecule that acts to catalyze specific biochemical reactions. (Section 14.7)
A compound with the structure R!O!R.
high-resolution mass spectrometry
A technique that involves the use of a detector that can measure the m/z values to four decimal places.This technique allows for the determination of the molecular formula of an unknown compound.
High-resolution mass spectrometry
Instrumentation that is capable of separating ions that differ in mass by as little as 0.0001 amu
inversion of configuration
During a reaction, when the configuration of a chirality center is changed.
In additionreactions, the observation that the hydrogen atomis generally placed at the vinylic position alreadybearing the larger number of hydrogen atoms.
Having no net overlap.
The structure that arises when a protein consists of two or more folded polypeptide chains that aggregate to form one protein complex.
A compound that can be used to achieve the resolution of enantiomers.
A theory that many molecules and ions are best described as a hybrid of several Lewis structures