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Solutions for Chapter 6.12: Regioselective, Stereoselective, And Stereospecific Reactions

Organic Chemistry | 8th Edition | ISBN: 9780134042282 | Authors: Paula Yurkanis Bruice

Full solutions for Organic Chemistry | 8th Edition

ISBN: 9780134042282

Organic Chemistry | 8th Edition | ISBN: 9780134042282 | Authors: Paula Yurkanis Bruice

Solutions for Chapter 6.12: Regioselective, Stereoselective, And Stereospecific Reactions

Solutions for Chapter 6.12
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Organic Chemistry was written by and is associated to the ISBN: 9780134042282. Chapter 6.12: Regioselective, Stereoselective, And Stereospecific Reactions includes 1 full step-by-step solutions. Since 1 problems in chapter 6.12: Regioselective, Stereoselective, And Stereospecific Reactions have been answered, more than 30855 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. This expansive textbook survival guide covers the following chapters and their solutions.

Key Chemistry Terms and definitions covered in this textbook
  • absorption spectrum

    A pattern of variation in the amount of light absorbed by a sample as a function of wavelength. (Section 23.5)

  • aldose

    A carbohydrate that contains an aldehyde group.

  • allylic

    The positions that are adjacent to the vinylic positions of a carboncarbon double bond.

  • amidomalonate synthesis

    A synthetic method that employs diethyl acetamidomalonate as the starting material and enables the preparation of racemic a-amino acids.

  • aqueous solution.

    A solution in which the solvent is water. (4.1)

  • bomb calorimeter

    A device for measuring the heat evolved in the combustion of a substance under constant-volume conditions. (Section 5.5)

  • carbonyl group

    A CRO bond. carboxylic acid derivative (Sect. 21.6): A compound that is similar in structure to a carboxylic acid (RCOOH) but the OH group of the carboxylic acid has been replaced with a different group, Z, where Z is a heteroatom such as Cl, O, N, etc. Nitriles (R!C#N) are also considered to be carboxylic acid derivatives because they have the same oxidation state as carboxylic acids.

  • excited state

    A state that is achieved when a compound absorbs energy.

  • Grignard reagent

    A carbanion with the structure RMgX.

  • halohydrin formation

    A reaction which involves the addition of a halogen and a hydroxyl group (OH) across an alkene.

  • Hell-Volhard-Zelinsky reaction

    A reaction in which a carboxylic acid undergoes a-halogenation when treated with bromine in the presence of PBr3.

  • Homotopic groups

    Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions

  • Lewis dot structure

    The symbol of an element surrounded by a number of dots equal to the number of electrons in the valence shell of the atom

  • nonaromatic

    A compound that lacks a ring with a continuous system of overlapping p orbitals.

  • Oligosaccharide

    A carbohydrate containing four to ten monosaccharide units, each joined to the next by a glycosidic bond.

  • Oxidation

    The loss of electrons. Alternatively, either the loss of hydrogens, the gain of oxygens, or both.

  • photon

    When electromagnetic radiation is viewed as a particle, an individual packet of energy.

  • specific rotation

    For a chiral compound that is subjected to plane-polarized light, the observed rotation when a standard concentration (1 g/mL) and a standard path length (1 dm) are used.

  • syndiotactic

    A polymer in which the repeating units contain chirality centers which have alternating configuration.

  • Upfield

    A signal of an NMR spectrum that is shifted toward the right (smaller chemical shift) on the chart paper.

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