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Solutions for Chapter 7.11: SYNTHESIS USING ACETYLIDE IONS

Organic Chemistry | 8th Edition | ISBN: 9780134042282 | Authors: Paula Yurkanis Bruice

Full solutions for Organic Chemistry | 8th Edition

ISBN: 9780134042282

Organic Chemistry | 8th Edition | ISBN: 9780134042282 | Authors: Paula Yurkanis Bruice

Solutions for Chapter 7.11: SYNTHESIS USING ACETYLIDE IONS

Solutions for Chapter 7.11
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This expansive textbook survival guide covers the following chapters and their solutions. Chapter 7.11: SYNTHESIS USING ACETYLIDE IONS includes 1 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. Organic Chemistry was written by and is associated to the ISBN: 9780134042282. Since 1 problems in chapter 7.11: SYNTHESIS USING ACETYLIDE IONS have been answered, more than 21464 students have viewed full step-by-step solutions from this chapter.

Key Chemistry Terms and definitions covered in this textbook
  • acylium ion

    The resonancestabilized, cationic intermediate of a Friedel-Crafts acylation, formed by treating an acyl halide with aluminum trichloride.

  • Alkyl group

    A group derived by removing a hydrogen from an alkane; given the symbol R!

  • Avogadro’s law.

    At constant pressure and temperature, the volume of a gas is directly proportional to the number of moles of the gas present. (5.3)

  • bonding atomic radius

    The radius of an atom as defined by the distances separating it from other atoms to which it is chemically bonded. (Section 7.3)

  • Chiral center

    A tetrahedral atom, most commonly carbon, that is bonded to four different groups; also called a chirality center

  • condensation polymerization

    Polymerization in which molecules are joined together through condensation reactions. (Section 12.8)

  • conjugate acid–base pair

    An acid and a base, such as H2O and OH-, that differ only in the presence or absence of a proton. (Section 16.2)

  • coupling constant

    When signal splitting occurs in NMR spectroscopy, the distance between the individual peaks of a signal.

  • denaturation

    A process during which a protein unfolds under conditions of mild heating.

  • dihedral angle

    The angle by which two groups are separated in a Newman projection.

  • Histone

    A protein, particularly rich in the basic amino acids lysine and arginine, that is found associated with DNA molecules

  • hydrohalogenation

    A reaction that involves the addition of H and X (either Br or Cl) across an alkene.

  • ketose

    A carbohydrate that contains a ketone group.

  • Levorotatory

    Refers to a substance that rotates the plane of polarized light to the left.

  • nucleophilic aromatic substitution

    A substitution reaction in which an aromatic ring is attacked by a nucleophile, which replaces a leaving group.

  • nucleosides

    The product formed when either d-ribose or 2-deoxy-d-ribose is coupled with certain nitrogen heterocycles (called bases).

  • octet rule

    A rule stating that bonded atoms tend to possess or share a total of eight valence-shell electrons. (Section 8.1)

  • polar covalent bond

    A covalent bond in which the electrons are not shared equally. (Section 8.4)

  • Thermoset plastic

    A polymer that can be molded when it is fi rst prepared, but once cooled, hardens irreversibly and cannot be remelted.

  • three-center, two-electron bonds

    A bond in which two electrons are associated with three atoms, such as in diborane (B2H6).

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