- 2.2.1: Do the line-angle formulas in each pair represent the same compound...
- 2.2.2: Draw line-angle formulas for the three constitutional isomers with ...
- 2.2.3: Write IUPAC names for these alkanes.
- 2.2.4: Combine the proper prefix, infix, and suffix and write the IUPAC na...
- 2.2.5: Write the molecular formula, IUPAC name, and common name for each c...
- 2.2.6: Write molecular formulas for each bicycloalkane, given its number o...
- 2.2.7: Following are the structural formulas and names of four bicycloalka...
- 2.2.8: For 1,2-dichloroethane:(a) Draw Newman projections for all eclipsed...
- 2.2.9: Following is a chair conformation of cyclohexane with the carbon at...
- 2.2.11: Draw a chair conformation of 1,4-dimethylcyclohexane in which one m...
- 2.2.12: Which cycloalkanes show cis,trans isomerism? For each that does, dr...
- 2.2.13: Following is a planar hexagon representation for one isomer of 1,2,...
- 2.2.14: Here is one cis,trans isomer of 3,5-dimethylcyclohexanol. Complete ...
- 2.2.15: Arrange the alkanes in each set in order of increasing boiling poin...
- 2.2.16: Write a line-angle formula for each condensed structural formula.
- 2.2.17: Write the molecular formula of each alkane.
- 2.2.18: Using parentheses and subscripts, provide an even more abbreviated ...
- 2.2.19: Which statements are true about constitutional isomers?(a) They hav...
- 2.2.21: an !OH (hydroxyl group, Section 1.3A). Which structural formulas re...
- 2.2.22: Each of the following compounds is an amine (Section 1.3B). Which s...
- 2.2.23: Each of the following compounds is either an aldehyde or a ketone (...
- 2.2.24: Draw structural formulas and write IUPAC names for the nine constit...
- 2.2.25: Draw structural formulas for all of the following.(a) Alcohols with...
- 2.2.26: Write IUPAC names for these alkanes and cycloalkanes.
- 2.2.27: Write structural formulas and line-angle formulas for the following...
- 2.2.28: Explain why each is an incorrect IUPAC name and write the correct I...
- 2.2.29: For each IUPAC name, draw the corresponding structural formula and ...
- 2.2.32: Torsional strain resulting from eclipsed C!H bonds is approximately...
- 2.2.33: How many different staggered conformations are there for 2-methylpr...
- 2.2.34: Consider 1-bromopropane, CH3CH2CH2Br.(a) Draw a Newman projection f...
- 2.2.35: Consider 1-bromo-2-methylpropane and draw the following.(a) The sta...
- 2.2.36: Trans-1,4-di-tert-butylcyclohexane exists in a normal chair conform...
- 2.2.37: From studies of the dipole moment of 1,2-dichloroethane in the gas ...
- 2.2.38: Draw structural formulas for the cis and trans isomers of hydrindan...
- 2.2.39: Following are the alternative chair conformations for trans-1,2-dim...
- 2.2.41: Is cis,trans isomerism possible in alkanes?
- 2.2.42: Draw structural formulas for the cis and trans isomers of 1,2-dimet...
- 2.2.43: Name and draw structural formulas for all cycloalkanes with molecul...
- 2.2.44: Using a planar pentagon representation for the cyclopentane ring, d...
- 2.2.45: Gibbs free energy differences between axial-substituted and equator...
- 2.2.46: When cyclohexane is substituted by an ethynyl group, !C#CH, the ene...
- 2.2.47: Calculate the difference in Gibbs free energy in kilojoules per mol...
- 2.2.48: Draw the alternative chair conformations for the cis and trans isom...
- 2.2.49: Use your answers from 2.48 to complete the table showing correlatio...
- 2.2.51: Draw alternative chair conformations for each substituted cyclohexa...
- 2.2.52: 1,2,3,4,5,6-Hexachlorocyclohexane shows cis,trans isomerism. At one...
- 2.2.53: In 2.24, you drew structural formulas for all isomeric alkanes with...
- 2.2.54: What generalization can you make about the densities of alkanes rel...
- 2.2.55: What unbranched alkane has about the same boiling point as water? (...
- 2.2.56: Complete and balance the following combustion reactions. Assume tha...
- 2.2.57: Following are heats of combustion per mole for methane, propane, an...
- 2.2.58: Following are structural formulas and heats of combustion of acetal...
- 2.2.59: Without consulting tables, arrange these compounds in order of decr...
- 2.2.61: Following are structural formulas for 1,4-dioxane and piperidine. 1...
- 2.2.62: Following is a planar hexagon representation of l-fucose, a sugar c...
- 2.2.63: stereorepresentation of glucose (we discuss the structure and chemi...
- 2.2.64: Following is the structural formula and a ball-and-stick model of c...
- 2.2.65: Following is the structural formula and a ball-and-stick model of c...
Solutions for Chapter 2: Constitutional Isomerism in Alkanes
Full solutions for Organic Chemistry | 7th Edition
ISBN: 9781133952848
Solutions for Chapter 2
16
1
Since 58 problems in chapter 2: Constitutional Isomerism in Alkanes have been answered, more than 13227 students have viewed full step-by-step solutions from this chapter. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 2: Constitutional Isomerism in Alkanes includes 58 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7. Organic Chemistry was written by and is associated to the ISBN: 9781133952848.
Key Chemistry Terms and definitions covered in this textbook
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Acyl group
An RCO! or ArCO! group.
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antibonding MO
A high-energy molecular orbital resulting from the destructive interference between atomic orbitals.
-
atmospheric pressure.
The pressure exerted by Earth’s atmosphere. (5.2)
-
bomb calorimeter
A device for measuring the heat evolved in the combustion of a substance under constant-volume conditions. (Section 5.5)
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cation.
An ion with a net positive charge. (2.5)
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common ion effect.
The shift in equilibrium caused by the addition of a compound having an ion in common with the dissolved substances. (16.2)
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equivalence point
The point in a titration at which the added solute reacts completely with the solute present in the solution. (Section 4.6)
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Haloarene (aryl halide)
A compound containing a halogen atom bonded to a benzene ring. Given the symbol Ar!X
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hydride shift
A type of carbocation rearrangement that involves the migration of a hydride ion (H-).
-
Lewis base
Any molecule or ion that can form a new covalent bond by donating a pair of electrons.
-
Lipid bilayer
A back-to-back arrangement of phospholipid monolayers, often forming a closed vesicle or membrane.
-
node
In atomic and molecular orbitals, a location where the value of y is zero.
-
optically pure
A solution containing just one enantiomer, but not its mirror image.
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Ostwald process
An industrial process used to make nitric acid from ammonia. The NH3 is catalytically oxidized by O2 to form NO; NO in air is oxidized to NO2; HNO3 is formed in a disproportionation reaction when NO2 dissolves in water. (Section 22.7)
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polar covalent bond
A bond in which the difference in electronegative values of the two atoms is between 0.5 and 1.7.
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Resonance in NMR spectroscopy
The absorption of electromagnetic radiation by a precessing nucleus and the resulting “fl ip” of its nuclear spin from the lower energy state to the higher energy state.
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Staggered conformation
A conformation about a carbon-carbon single bond in which the atoms or groups on one carbon are as far apart as possible from atoms or groups on an adjacent carbon.
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sulfoxide
A compound containing an SRO bond that is flanked on both sides by R groups.
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syn-coplanar
A conformation in which a hydrogen atom and a leaving group are separated by a dihedral angle of exactly 0°.
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Triol
A compound containing three hydroxyl groups.