Solutions for Chapter 4: Acids and Bases

Naturally occurring amines isolated from plants.

Properties of solutions that depend on the number of solute particles in solution and not on the nature of the solute particles. (12.6)

A semiconducting material formed from two or more elements. (Section 12.7)

A drawing style in which none of the bonds are drawn. Groups of atoms are clustered together when possible. For example, isopropanol has two CH3 groups, both of which are connected to the central carbon atom, shown like this: (CH3)2CHOH.

The pressure at which a gas at its critical temperature is converted to a liquid state. (Section 11.4)

A techniquefor performing a crossed aldol addition thatproduces one major product.

The number of full cycles of a wave that pass a given point in a second, and reported in hertz (Hz), which has the units s21

A conformation that exhibits a gauche interaction.

The enthalpy change, ?H, for vaporization of a liquid. (Section 11.4)

A measure of the strength of an acid: Ka = Keq 3H2O4 = 3H3O+ 4 3A- 4 3HA4

An ion or molecule that coordinates to a metal atom or to a metal ion to form a complex. (Section 23.2)

A polymer that isformed via anionic polymerization.

Plasma particles, density 1.02–1.06 g/mL, consisting of approximately 26% proteins, 50% cholesterol, 21% phospholipids, and 4% triglycerides.

An organic compound containing at least one halogen.

Units used on NMR spectra to record chemical shift relative to the TMS standard.

An amine in which nitrogen is bonded to one carbon and two hydrogens

One of the four arrow-pushing patterns for ionic reactions.

A theory that many molecules and ions are best described as a hybrid of several Lewis structures

A conformational change in which one chair conformation is converted into the other.

Polymers that are formed under conditions in which the individual monomers react with each other to form oligomers, which are then joined together to form polymers.