- 8.8.1: Write the IUPAC name, and where possible, the common name of each c...
- 8.8.2: Name and draw structural formulas for all monochlorination products...
- 8.8.3: Using the table of bond dissociation enthalpies in Appendix 3, calc...
- 8.8.4: Write a pair of chain propagation steps for the radical bromination...
- 8.8.5: Given the solution to Example 8.5, predict the structure of the pro...
- 8.8.6: Show the products of the following reaction and indicate the major ...
- 8.8.7: Predict the major product of the following reaction:
- 8.8.8: Give IUPAC names for the following compounds. Where stereochemistry...
- 8.8.9: Draw structural formulas for the following compounds.(a) 3-Iodo-1-p...
- 8.8.11: The boiling point of methylcyclohexane (C7H14, MW 98.2) is 101C. Th...
- 8.8.12: Account for the fact that among the chlorinated derivatives of meth...
- 8.8.13: Name and draw structural formulas for all possible monohalogenation...
- 8.8.14: Which compounds can be prepared in high yield by halogenation of an...
- 8.8.15: 8.15 There are three constitutional isomers with the molecular form...
- 8.8.16: 8.16 Following is a balanced equation for bromination of toluene.C6...
- 8.8.18: Following are balanced equations for fluorination of propane to pro...
- 8.8.19: As you demonstrated in 8.18, fluorination of alkanes is highly exot...
- 8.8.21: first chain propagation step of all radical halogenation reactions ...
- 8.8.22: Following is a balanced equation for the allylic bromination of pro...
- 8.8.23: Using the table of bond dissociation enthalpies (Appendix 3), estim...
- 8.8.24: Propose a series of chain initiation, propagation, and termination ...
- 8.8.25: The major product formed when methylenecyclohexane is treated with ...
- 8.8.26: Draw the structural formula of the products formed when each alkene...
- 8.8.27: Calculate the DH0 for the following reaction step. What can you say...
- 8.8.28: Use the roadmap you made for 6.54 and 7.29 and update it to contain...
- 8.8.29: Write the products of the following sequences of reactions. Refer t...
- 8.8.31: Predict the products of the following reactions. Where isomeric pro...
- 8.8.32: Give the major product of the following reactions.
- 8.8.33: A major use of the compound cumene is in the industrial preparation...
- 8.8.34: An important use of radical-chain reactions is in the polymerizatio...
Solutions for Chapter 8: Haloalkanes, Halogenation, and Radical Reactions
Full solutions for Organic Chemistry | 7th Edition
ISBN: 9781133952848
Chapter 8: Haloalkanes, Halogenation, and Radical Reactions includes 30 full step-by-step solutions. This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry was written by and is associated to the ISBN: 9781133952848. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7. Since 30 problems in chapter 8: Haloalkanes, Halogenation, and Radical Reactions have been answered, more than 56739 students have viewed full step-by-step solutions from this chapter.
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alkali metals.
The Group 1A elements (Li, Na, K, Rb, Cs, and Fr). (2.4)
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Chair conformation
The most stable nonplanar conformation of a cyclohexane ring; all bond angles are approximately 109.5°, and all bonds on adjacent carbons are staggered.
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degenerate
A situation in which two or more orbitals have the same energy. (Section 6.7)
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electron shell
A collection of orbitals that have the same value of n. For example, the orbitals with n = 3 (the 3s, 3p, and 3d orbitals) comprise the third shell. (Section 6.5)
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Electrophilic aromatic substitution
A reaction in which there is substitution of an electrophile, E1, for a hydrogen on an aromatic ring
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Hell-Volhard-Zelinsky reaction
A reaction in which a carboxylic acid undergoes a-halogenation when treated with bromine in the presence of PBr3.
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Hess’s law
The heat evolved in a given process can be expressed as the sum of the heats of several processes that, when added, yield the process of interest. (Section 5.6)
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intermetallic compound
A homogeneous alloy with definite properties and a fixed composition. Intermetallic compounds are stoichiometric compounds that form between metallic elements. (Section 12.3)
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matter
Anything that occupies space and has mass; the physical material of the universe. (Section 1.1)
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observed rotation
The extent to which plane-polarized light is rotated by a solution of a chiral compound.
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oxidation
A reaction in which one compound undergoes an increase in oxidation state.
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peptide
A chain comprised of a small number of amino acid residues.
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phosphoglycerides
Compounds that are very similar in structure to triglycerides, with the main difference being that one of the three fatty acid residues is replaced by a phosphoester group.
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reducing sugar
A carbohydrate that is oxidized upon treatment with Tollens’ reagent, Fehling’s reagent, or Benedict’s reagent.
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Solvolysis
A nucleophilic substitution in which the solvent is also the nucleophile
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specific rotation
For a chiral compound that is subjected to plane-polarized light, the observed rotation when a standard concentration (1 g/mL) and a standard path length (1 dm) are used.
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Steric hindrance
The ability of groups, because of their size, to hinder access to a reaction site within a molecule.
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sulfide
A compound that is similar in structure to an ether, but the oxygen atom has been replaced with a sulfur atom. Also called a thioether.
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tertiary alkyl halide
An organohalide in which the alpha (a) position is connected to three alkyl groups.
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wedge
In bond-line structures, a group in front of the page.