- 23.5SE.1PE: Predicting Whether a Complex Has Optical IsomersDoes either have op...
- 23.5SE.2PE: ?blem 2PEPredicting Whether a Complex Has Optical IsomersDoes eithe...
Solutions for Chapter 23.5SE: Chemistry: The Central Science 13th Edition
Full solutions for Chemistry: The Central Science | 13th Edition
ISBN: 9780321910417
Chapter 23.5SE includes 2 full step-by-step solutions. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 13. Since 2 problems in chapter 23.5SE have been answered, more than 146232 students have viewed full step-by-step solutions from this chapter. This expansive textbook survival guide covers the following chapters and their solutions. Chemistry: The Central Science was written by and is associated to the ISBN: 9780321910417.
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activate
For a substituted aromatic ring, the effect of an electron-donating substituent that increases the rate of electrophilic aromatic substitution.
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aromatic hydrocarbons
Hydrocarbon compounds that contain a planar, cyclic arrangement of carbon atoms linked by both s and delocalized p bonds. (Section 24.2)
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b-Pleated sheet
A type of polypeptide secondary structure in which sections of polypeptide chains are aligned parallel or antiparallel to one another.
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bimolecular
For mechanisms, a step that involves two chemical entities.
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bond-line structures
The most common drawing style employed by organic chemists. All carbon atoms and most hydrogen atoms are implied but not explicitly drawn in a bond-line structure.
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crystal-field theory
A theory that accounts for the colors and the magnetic and other properties of transition-metal complexes in terms of the splitting of the energies of metal ion d orbitals by the electrostatic interaction with the ligands. (Section 23.6)
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Decarboxylation
Loss of CO2 from a carboxyl group.
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diagonal relationship.
Similarities between pairs of elements in different groups and periods of the periodic table. (8.6)
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enantiotopic
Protons that are not interchangeable by rotational symmetry but are interchangeable by reflectional symmetry.
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fuel cell
A voltaic cell that utilizes the oxidation of a conventional fuel, such as H2 or CH4, in the cell reaction. (Section 20.7)
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Gibbs free energy
A thermodynamic state function that combines enthalpy and entropy, in the form G = H - TS. For a change occurring at constant temperature and pressure, the change in free energy is ?G = ?H - T?S. (Section 19.5)
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heterolytic bond cleavage
Bond breaking that results in the formation of ions.
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low-spin complex
A metal complex in which the electrons are paired in lower-energy orbitals. (Section 23.6)
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Organic synthesis
A series of reactions by which a set of organic starting materials is converted to a more complicated structure.
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parts per million (ppm)
The concentration of a solution in grams of solute per 106 (million) grams of solution; equals milligrams of solute per liter of solution for aqueous solutions. (Section 13.4)
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quantitative analysis
The determination of the amount of a given substance that is present in a sample. (Section 17.7)
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reducing agent
A compound that reduces another compound and in the process is itself oxidized. Sodium borohydride and lithium aluminum hydride are reducing agents.
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second-order reaction
A reaction in which the overall reaction order (the sum of the concentration- term exponents) in the rate law is 2. (Section 14.4)
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sulfonation
An electrophilic aromatic substitution reaction in which an SO3H group is installed on an aromatic ring.
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torsional strain
The difference in energy between staggered and eclipsed conformations (for example, in ethane).