- 14.14SE.2PE: Determining the Rate Law for a Multistep MechanismThe decomposition...
- 14.14SE.1PE: Determining the Rate Law fora Multistep MechanismThe decomposition ...
Solutions for Chapter 14.14SE: Chemistry: The Central Science 13th Edition
Full solutions for Chemistry: The Central Science | 13th Edition
An organic compound that contains a carbonyl group 1C “O2 to which at least one hydrogen atom is attached. (Section 24.4)
A reaction in which two alkenes interchange the carbons attached to their double bonds.
A substance that has the characteristic properties of a metal and contains more than one element. Often there is one principal metallic component, with other elements present in smaller amounts. Alloys may be homogeneous or heterogeneous. (Section 12.3)
A statement that the volume of a gas maintained at constant temperature and pressure is directly proportional to the number of moles of the gas. (Section 10.3)
For chair conformations of substituted cyclohexanes, a position that is parallel to a vertical axis passing through the center of the ring.
Energy stored within the structural units of chemical substances. (6.1)
Alkanes whose carbon atoms are joined in rings. (24.2)
The process in which the molecules go directly from the vapor into the solid phase. (11.8)
A device in which a nonspontaneous oxidation–reduction reaction is caused to occur by passage of current under a sufficient external electrical potential. (Section 20.9)
free induction decay
In NMR spectroscopy, a complex signal which is a combination of all of the electrical impulses generated by each type of proton.
A reaction which involves the addition of a halogen and a hydroxyl group (OH) across an alkene.
A substance that exhibits one or more partially ordered liquid phases above the melting point of the solid form. By contrast, in nonliquid crystalline substances the liquid phase that forms upon melting is completely unordered. (Section 11.7)
A polymer chain that continues to grow without chain-termination steps until either all of the monomer is consumed or some external agent is added to terminate the chain. The polymer chains will continue to grow if more monomer is added.
An analytical technique for measuring the mass-to-charge ratio (m/z) of ions.
molecular orbital (MO)
An allowed state for an electron in a molecule. According to molecular-orbital theory, a molecular orbital is entirely analogous to an atomic orbital, which is an allowed state for an electron in an atom. Most bonding molecular orbitals can be classified as s or p, depending on the disposition of electron density with respect to the internuclear axis. (Section 9.7)
A compound that contains an !OH bonded to a benzene ring; a benzenol.
The ability of an atom or molecule to distribute its electron density unevenly in response to external influences.
A macromolecule containing many amino acid units, each joined to the next by a peptide bond
The manner in which a protein is coiled or stretched. (Section 24.7)
A bimolecular nucleophilic substitution reaction.
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