- 11.11.22: Draw all resonance structures for each of the following radicals: (...
- 11.11.23: Consider all of the different C!H bonds in cyclopentene and rank th...
- 11.11.24: Rank each group of radicals in order of increasing stability: (a) (b)
- 11.11.25: Draw all resonance structures of the radical produced when a hydrog...
- 11.11.26: When isopropylbenzene (cumene) is treated with NBS and irradiated w...
- 11.11.27: here are three constitutional isomers with the molecular formula C5...
- 11.11.28: When ethylbenzene is treated with NBS and irradiated with UV light,...
- 11.11.29: AIBN is an azo compound (a compound with a NRN double bond) that is...
- 11.11.3: Triphenylmethane readily undergoes autooxidation to produce a hydro...
- 11.11.31: For each of the products shown in the following reaction, propose a...
- 11.11.32: Abstraction of a hydrogen atom from 3-ethylpentane can yield three ...
- 11.11.33: Identify the major product(s) for each of the following reactions. ...
- 11.11.34: Chlorination of (S)-2-chloropentane produces a mixture of isomers w...
- 11.11.35: Predict the major product(s) obtained upon bromination of (S)-3-met...
- 11.11.36: Identify all products expected for each of the following reactions....
- 11.11.37: Draw the propagation steps that achieve the autooxidation of diethy...
- 11.11.38: Compound A has molecular formula C5H12, and monobromination of comp...
- 11.11.39: Draw the products obtained when 3,3,6-trimethylcyclohexene is treat...
- 11.11.4: When 2-methylpropane is treated with bromine in the presence of UV ...
- 11.11.41: Consider the structure of the following compound: (a) When this com...
- 11.11.42: The rate at which two methyl radicals couple to form ethane is sign...
- 11.11.43: How many constitutional isomers are obtained when each of the follo...
- 11.11.44: Using acetylene and 2-methylpropane as your only sources of carbon ...
- 11.11.45: Propose an efficient synthesis for each of the following transforma...
- 11.11.46: Consider the following two compounds. Monochlorination of one of th...
- 11.11.47: When butane reacts with Br2 in the presence of Cl2, both brominated...
- 11.11.48: When an acyl peroxide undergoes homolytic bond cleavage, the radica...
- 11.11.49: Consider the following radical process, called a thiol-ene coupling...
- 11.11.5: Commercial samples of pentacene (A) generally contain small amounts...
- 11.11.51: The alkyl halide 1-bromopropane is one of a number of compounds bei...
- 11.11.52: One strategy for the synthesis of complicated polycyclic ring syste...
- 11.11.53: Compounds with the structure ArNRNCONRNAr (where Ar represents an a...
- 11.11.54: As seen in this chapter, hydrocarbons typically do not undergo radi...
- 11.11.55: Resveratrol is a naturally occurring antioxidant found in a broad r...
- 11.11.56: In Chapter 2, we saw several patterns for drawing resonance structu...
- 11.11.57: Compound 2 was used as a key intermediate in a synthesis of oseltam...
- 11.11.58: The Kharasch reaction is a radical process in which carbon tetrachl...
- 11.11.59: The ring-forming reaction below (initiated by heat) is believed to ...
Solutions for Chapter 11: Organic Chemistry 2nd Edition
Full solutions for Organic Chemistry | 2nd Edition
ISBN: 9781118454312
Solutions for Chapter 11
17
2
This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry was written by and is associated to the ISBN: 9781118454312. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 2. Chapter 11 includes 38 full step-by-step solutions. Since 38 problems in chapter 11 have been answered, more than 106566 students have viewed full step-by-step solutions from this chapter.
Key Chemistry Terms and definitions covered in this textbook
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actinide element
Element in which the 5f orbitals are only partially occupied. (Section 6.8)
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alkyl halide
An organic compound containing at least one halogen.
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aqueous solution.
A solution in which the solvent is water. (4.1)
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Benzyne intermediate
A reactive intermediate formed by b-elimination from adjacent carbon atoms of a benzene ring and having a triple bond in the benzene ring. The second p bond of the benzyne triple bond is formed by the weak overlap of coplanar 2p orbitals on adjacent carbons.
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Carbonyl group (Section 1.3C)
A C"O group.
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complex ion (complex)
An assembly of a metal ion and the Lewis bases (ligands) bonded to it. (Section 17.5)
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deactivate
For a substitutedaromatic ring, the effect of an electronwithdrawingsubstituent that decreases therate of electrophilic aromatic substitution.
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dihydroxylation
A reaction characterized by the addition of two hydroxyl groups (OH) across an alkene.
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electrochemistry
The branch of chemistry that deals with the relationships between electricity and chemical reactions. (Chapter 20: Introduction)
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electrophoresis
A technique for separating amino acids from each other based on a difference in pI values.
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enthalpy
A measure of the exchange of energy between the system and its surroundings during any process.
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ester
An organic compound that has an OR group attached to a carbonyl; it is the product of a reaction between a carboxylic acid and an alcohol. (Section 24.4)
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Hund’s rule
When orbitals of equal energy are available but there are not enough electrons to fi ll all of them completely, one electron is put in each before a second electron is added to any
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Lipid bilayer
A back-to-back arrangement of phospholipid monolayers, often forming a closed vesicle or membrane.
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locant
In nomenclature, a numberused to identify the location of a substituent.
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regioselective
A reaction that can produce two or more constitutional isomers but nevertheless produces one as the major product.
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steric number
The total of (single bonds + lone pairs) for an atom in a compound.
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syn addition
An addition reaction in which two groups are added to the same face of a p bond.
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Tertiary (3°) amine
An amine in which nitrogen is bonded to three carbons
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wavelength
The distance between adjacent peaks of an oscillating magnetic or electric field.