- 11.11.22: Draw all resonance structures for each of the following radicals: (...
- 11.11.23: Consider all of the different C!H bonds in cyclopentene and rank th...
- 11.11.24: Rank each group of radicals in order of increasing stability: (a) (b)
- 11.11.25: Draw all resonance structures of the radical produced when a hydrog...
- 11.11.26: When isopropylbenzene (cumene) is treated with NBS and irradiated w...
- 11.11.27: here are three constitutional isomers with the molecular formula C5...
- 11.11.28: When ethylbenzene is treated with NBS and irradiated with UV light,...
- 11.11.29: AIBN is an azo compound (a compound with a NRN double bond) that is...
- 11.11.3: Triphenylmethane readily undergoes autooxidation to produce a hydro...
- 11.11.31: For each of the products shown in the following reaction, propose a...
- 11.11.32: Abstraction of a hydrogen atom from 3-ethylpentane can yield three ...
- 11.11.33: Identify the major product(s) for each of the following reactions. ...
- 11.11.34: Chlorination of (S)-2-chloropentane produces a mixture of isomers w...
- 11.11.35: Predict the major product(s) obtained upon bromination of (S)-3-met...
- 11.11.36: Identify all products expected for each of the following reactions....
- 11.11.37: Draw the propagation steps that achieve the autooxidation of diethy...
- 11.11.38: Compound A has molecular formula C5H12, and monobromination of comp...
- 11.11.39: Draw the products obtained when 3,3,6-trimethylcyclohexene is treat...
- 11.11.4: When 2-methylpropane is treated with bromine in the presence of UV ...
- 11.11.41: Consider the structure of the following compound: (a) When this com...
- 11.11.42: The rate at which two methyl radicals couple to form ethane is sign...
- 11.11.43: How many constitutional isomers are obtained when each of the follo...
- 11.11.44: Using acetylene and 2-methylpropane as your only sources of carbon ...
- 11.11.45: Propose an efficient synthesis for each of the following transforma...
- 11.11.46: Consider the following two compounds. Monochlorination of one of th...
- 11.11.47: When butane reacts with Br2 in the presence of Cl2, both brominated...
- 11.11.48: When an acyl peroxide undergoes homolytic bond cleavage, the radica...
- 11.11.49: Consider the following radical process, called a thiol-ene coupling...
- 11.11.5: Commercial samples of pentacene (A) generally contain small amounts...
- 11.11.51: The alkyl halide 1-bromopropane is one of a number of compounds bei...
- 11.11.52: One strategy for the synthesis of complicated polycyclic ring syste...
- 11.11.53: Compounds with the structure ArNRNCONRNAr (where Ar represents an a...
- 11.11.54: As seen in this chapter, hydrocarbons typically do not undergo radi...
- 11.11.55: Resveratrol is a naturally occurring antioxidant found in a broad r...
- 11.11.56: In Chapter 2, we saw several patterns for drawing resonance structu...
- 11.11.57: Compound 2 was used as a key intermediate in a synthesis of oseltam...
- 11.11.58: The Kharasch reaction is a radical process in which carbon tetrachl...
- 11.11.59: The ring-forming reaction below (initiated by heat) is believed to ...
Solutions for Chapter 11: Radical Reactions
Full solutions for Organic Chemistry | 2nd Edition
ISBN: 9781118454312
Solutions for Chapter 11
17
2
Summary of Chapter 11: Radical Reactions
This chapter will focus on radicals, their structure and reactivity. Explore some of the important roles they play in the food and chemical industries and in our overall health.
This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry was written by and is associated to the ISBN: 9781118454312. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 2. Chapter 11: Radical Reactions includes 38 full step-by-step solutions. Since 38 problems in chapter 11: Radical Reactions have been answered, more than 294096 students have viewed full step-by-step solutions from this chapter.
Key Chemistry Terms and definitions covered in this textbook
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activity series.
A summary of the results of many possible displacement reactions. (4.4)
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Acylium ion
A resonance-stabilized cation with the structure [RC"O]1 or [ArC"O]1. The positive charge is delocalized over both the carbonyl carbon and the carbonyl oxygen.
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Anti stereoselectivity
The addition of atoms or groups of atoms to opposite faces of a carbon-carbon double bond.
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buffered solution (buffer)
A solution that undergoes a limited change in pH upon addition of a small amount of acid or base. (Section 17.2)
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colloids (colloidal dispersions)
Mixtures containing particles larger than normal solutes but small enough to remain suspended in the dispersing medium. (Section 13.6)
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complex ion (complex)
An assembly of a metal ion and the Lewis bases (ligands) bonded to it. (Section 17.5)
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conductor.
Substance capable of conducting electric current. (21.3)
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coupling constant
When signal splitting occurs in NMR spectroscopy, the distance between the individual peaks of a signal.
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covalent bond.
A bond in which two electrons are shared by two atoms. (9.4)
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dextrorotatory
A compound that rotates plane-polarized light in a clockwise direction (+).
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face-centered lattice
A crystal lattice in which the lattice points are located at the faces and corners of each unit cell. (Section 12.2)
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Faraday constant (F )
The magnitude of charge of one mole of electrons: 96,500 C>mol. (Section 20.5)
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formation constant
For a metal ion complex, the equilibrium constant for formation of the complex from the metal ion and base species present in solution. It is a measure of the tendency of the complex to form. (Section 17.5)
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isotopes
Atoms of the same element containing different numbers of neutrons and therefore having different masses. (Section 2.3)
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Kinetic control
Experimental conditions under which the composition of the product mixture is determined by the relative rates of formation of each product.
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Lewis base
A compound capable offunctioning as an electron pair donor.
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rate equation
An equation thatdescribes the relationship between the rate of a reactionand the concentration of reactants.
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SN2
A bimolecular nucleophilic substitution reaction.
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sp2 Hybrid orbital
A hybrid atomic orbital formed by the combination of one s atomic orbital and two 2p atomic orbitals.
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spectator ions
Ions that go through a reaction unchanged and that appear on both sides of the complete ionic equation. (Section 4.2)