Solutions for Chapter 14: Organic Chemistry 6th Edition

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown and Lawrence S. Brown

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9780840054982

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown and Lawrence S. Brown

Solutions for Chapter 14

Solutions for Chapter 14
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Textbook: Organic Chemistry
Edition: 6
Author: William H. Brown and Lawrence S. Brown
ISBN: 9780840054982

This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. Since 35 problems in chapter 14 have been answered, more than 18778 students have viewed full step-by-step solutions from this chapter. Organic Chemistry was written by Sieva Kozinsky and is associated to the ISBN: 9780840054982. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 14 includes 35 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • alkoxide

    The conjugate base of an alcohol.

  • Alkyl group

    A group derived by removing a hydrogen from an alkane; given the symbol R!

  • anomers

    Stereoisomeric cyclic hemiacetals of an aldose or ketose that differ from each other in their configuration at the anomeric carbon.

  • blocking group

    A group that can be readily installed and uninstalled. Used for regiochemical control during synthesis.

  • cell potential

    The potential difference between the cathode and anode in an electrochemical cell; it is measured in volts: 1 V = 1 J>C. Also called electromotive force. (Section 20.4)

  • condensation.

    The phenomenon of going from the gaseous state to the liquid state. (11.8)

  • diatomic molecule

    A molecule composed of only two atoms. (Section 2.6)

  • Enamine

    An unsaturated compound derived by the reaction of an aldehyde or ketone and a secondary amine followed by loss of H2O; R2C"CR!NR2

  • estrogens

    Female sex hormones.

  • Excited state

    A state of a system at higher energy than the ground state.

  • Fischer esterifi cation

    The process of forming an ester by refl uxing a carboxylic acid and an alcohol in the presence of an acid catalyst, commonly H2SO4, ArSO3H, or HCl

  • High-density lipoprotein (HDL)

    Plasma particles, density 1.06–1.21 g/mL, consisting of approximately 33% proteins, 30% cholesterol, 29% phospholipids, and 8% triglycerides.

  • IUPAC

    The International Union of Pure and Applied Chemistry

  • Meisenheimer complex

    Theresonance-stabilized intermediate of a nucleophilicaromatic substitution reaction.

  • metallic hydrides

    Compounds formed when hydrogen reacts with transition metals; these compounds contain the hydride ion, H-. (Section 22.2)

  • mole

    A collection of Avogadro’s number 16.022 * 10232 of objects; for example, a mole of H2O is 6.022 * 1023 H2O molecules. (Section 3.4)

  • Mutarotation

    The change in specifi c rotation that occurs when an a or b hemiacetal form of a carbohydrate in aqueous solution is converted to an equilibrium mixture of the two forms.

  • peptide

    A chain comprised of a small number of amino acid residues.

  • Robinson annulation

    The combination of a Michael addition followed by an aldol condensation to form a ring.

  • triglyceride

    A triester formed from glycerol and three long-chain carboxylic acids.

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