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Solutions for Chapter 27: Organic Chemistry 6th Edition

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown, Christopher S. Foote , Brent L. Iverson, Eric Anslyn

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9780840054982

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown, Christopher S. Foote , Brent L. Iverson, Eric Anslyn

Solutions for Chapter 27

Solutions for Chapter 27
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Textbook: Organic Chemistry
Edition: 6
Author: William H. Brown, Christopher S. Foote , Brent L. Iverson, Eric Anslyn
ISBN: 9780840054982

This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. Chapter 27 includes 52 full step-by-step solutions. Since 52 problems in chapter 27 have been answered, more than 38309 students have viewed full step-by-step solutions from this chapter. Organic Chemistry was written by and is associated to the ISBN: 9780840054982.

Key Chemistry Terms and definitions covered in this textbook
  • accuracy.

    The closeness of a measurement to the true value of the quantity that is measured. (1.8)

  • alkali metals.

    The Group 1A elements (Li, Na, K, Rb, Cs, and Fr). (2.4)

  • Alkoxy group

    An !OR group where R is an alkyl group

  • alpha (a) helix

    For proteins, a feature of secondary structure that forms when a portion of the protein twists into a spiral.

  • anti-coplanar

    A conformation in which a hydrogen atom and a leaving group are separated by a dihedral angle of exactly 180°.

  • beta (b) position

    The position immediately adjacent to an alpha (a) position.

  • Brønsted-Lowry base

    A proton acceptor

  • capillary action

    The process by which a liquid rises in a tube because of a combination of adhesion to the walls of the tube and cohesion between liquid particles. (Section 11.3)

  • Claisen rearrangement

    A [3,3] sigmatropic rearrangement that is observed for allylic vinylic ethers.

  • d–d transition

    The transition of an electron in a transition-metal compound from a lower-energy d orbital to a higher-energy d orbital. (Section 23.6)

  • enzymes

    Important biological molecules that catalyze virtually all cellular processes.

  • Friedel-Crafts alkylation

    An electrophilic aromatic substitution reaction that installs an alkyl group on an aromatic ring.

  • Haloform

    A compound of the type CHX3 where X is a halogen.

  • Hydrogen bonding

    The attractive interaction between a hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of high electronegativity (again, most commonly O or N).

  • primary alkyl halide

    An organohalide in which the alpha (a) position is connected to only one alkyl group.

  • Prochiral hydrogens

    Refers to two hydrogens bonded to a carbon atom. When a different atom replaces one or the other, the carbon becomes a chiral center. The hydrogens of the CH2 group of ethanol, for example, are prochiral. Replacing one of them by deuterium gives (R)-1-deuteroethanol; replacing the other gives (S)-1-deuteroethanol

  • proton

    A positively charged subatomic particle found in the nucleus of an atom. (Section 2.3)

  • Quaternary (4°) ammonium ion

    An ion in which nitrogen is bonded to four carbons and bears a positive charge

  • ring flip

    A conformational change in which one chair conformation is converted into the other.

  • symmetrical ether

    An ether (R!O!R) where both R groups are identical.

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