Electroosmotic velocities of buffered solutions are shown for a bare silica capillary

Chapter 25, Problem 25-24

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Electroosmotic velocities of buffered solutions are shown for a bare silica capillary and one with aminopropyl groups (silicaSiCH2CH2CH2NH2) covalently attached to the wall. A positive sign means that flow is toward the cathode. Explain the signs and relative magnitudes of the velocities. Electroosmotic velocity (mm/s) for E 4.0 104 V/m Capillary wall pH 10 pH 2.5 Bare silica 3.1 0.2 Aminopropyl-modified silica 1.8 1.3 SOURCE: K. Emoto, J. M. Harris, and M. Van Alstine, Grafting Poly(ethylene glycol) Epoxide to Amino-Derivatized Quartz: Effect of Temperature and pH on Grafting Density, Anal. Chem. 1996, 68, 3751. 25

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