Solved: (a) Sketch the pi molecular orbitals of hexa-1,3,5-triene (Figure 15-25). (b)

Chapter 0, Problem 15-35

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(a) Sketch the pi molecular orbitals of hexa-1,3,5-triene (Figure 15-25). (b) Show the electronic configuration of the ground state of hexa-1,3,5-triene. (c) Show what product would result from the cycloaddition of hexa-1,3,5-triene with maleic anhydride. [6 + 2] (d) Show that the cyclization of hexa-1,3,5-triene with maleic anhydride is thermally forbidden but photochemically allowed.

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