?(a) Explain why \(\mathrm{BrF}_{4}^{-}\) is square planar, whereas \(\mathrm{BF}_{4}^{-}\) is tetrahedral. (b) How would you expect the H-X-

Chapter 9, Problem 9.33

(choose chapter or problem)

(a) Explain why \(\mathrm{BrF}_{4}^{-}\) is square planar, whereas \(\mathrm{BF}_{4}^{-}\) is tetrahedral.

(b) How would you expect the H-X-H bond angle to vary in the series \(\mathrm{H}_{2} \mathrm{O}, \mathrm{H}_{2} \mathrm{~S}, \mathrm{H}_{2} \mathrm{Se}\)? Explain. (Hint: The size of an electron pair domain depends in part on the electronegativity of the central atom.)

Text Transcription:

BrF_4^ -

BF_4^ -

H_2O, H_2S, H_2Se

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