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Write the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) hexaamminechromium(III) n

Chemistry: The Central Science | 14th Edition | ISBN: 9780134414232 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus ISBN: 9780134414232 1274

Solution for problem 23.35 Chapter 23

Chemistry: The Central Science | 14th Edition

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Chemistry: The Central Science | 14th Edition | ISBN: 9780134414232 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus

Chemistry: The Central Science | 14th Edition

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Problem 23.35 Write the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) hexaamminechromium(III) nitrate (b) tetraamminecarbonatocobalt(III) sulfate (c) dichlorobis(ethylenediamine)platinum(IV) bromide (d) potassium diaquatetrabromovanadate(III) (e) bis(ethylenediamine)zinc(II) tetraiodomercurate(II)
Step-by-Step Solution:

Step 1 of 5) The magnetic behavior can be used to determine whether this compound is a low-spin or high-spin complex. Since there is a single peak in the visible absorption spectrum, the color of the compound should be complementary to the color of light that is absorbed most strongly. There are six valence electrons in the d orbitals. The filling of the t2 and e orbitals for both high-spin and low-spin complexes is shown below. Because the compound is diamagnetic, we know all of the electrons must be paired up, which allows us to determine that it is a low-spin complex.We are told that the compound is orange and has a single absorption peak in the visible region of the spectrum. The compound must therefore absorb the complementary color of orange, which is blue. The blue region of the spectrum ranges from approximately 430 nm to 490 nm. As an estimate we assume that the complex ion absorbs somewhere in the middle of the blue region, near 460 nm.

Step 2 of 2

Chapter 23, Problem 23.35 is Solved
Textbook: Chemistry: The Central Science
Edition: 14
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus
ISBN: 9780134414232

This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 14. The full step-by-step solution to problem: 23.35 from chapter: 23 was answered by , our top Chemistry solution expert on 10/03/18, 06:29PM. This full solution covers the following key subjects: . This expansive textbook survival guide covers 29 chapters, and 2820 solutions. The answer to “Write the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) hexaamminechromium(III) nitrate (b) tetraamminecarbonatocobalt(III) sulfate (c) dichlorobis(ethylenediamine)platinum(IV) bromide (d) potassium diaquatetrabromovanadate(III) (e) bis(ethylenediamine)zinc(II) tetraiodomercurate(II)” is broken down into a number of easy to follow steps, and 34 words. Chemistry: The Central Science was written by and is associated to the ISBN: 9780134414232. Since the solution to 23.35 from 23 chapter was answered, more than 218 students have viewed the full step-by-step answer.

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Write the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) hexaamminechromium(III) n