?Use the collision theory of gas-phase reactions to calculate the theoretical value of

Chapter 18, Problem E18A.4(b)

(choose chapter or problem)

Use the collision theory of gas-phase reactions to calculate the theoretical value of the second-order rate constant for the elementary reaction \(\mathrm{D}_{2}+\mathrm{Br}_{2} \rightarrow \mathrm{DBr}+\mathrm{DBr}\) at 450 K. Take the collision cross-section as \(0.30 \mathrm{\ nm}^{2}\) , the reduced mass as \(3.930 m_{\mathrm{u}}\), and the activation energy as \(200 \mathrm{\ kJ} \mathrm{\ mol}^{-1}\) . (Assume a steric factor of 1.)

Text Transcription:

D_2+Br_2 rightarrow DBr+DBr

0.30 nm^2

3.930m_u

200 kJ mol^-1

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