?Solid \(\mathrm{NH}_{4} \mathrm{SH}\) is introduced into an evacuated flask at

Chapter 15, Problem 15.81

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Solid \(\mathrm{NH}_{4} \mathrm{SH}\) is introduced into an evacuated flask at \(24^{\circ} \mathrm{C}\). The following reaction takes place:

\(\mathrm{NH}_{4} \mathrm{SH}(s) \rightleftharpoons \mathrm{NH}_{3}(g)+\mathrm{H}_{2} \mathrm{~S}(g)\)

At equilibrium, the total pressure (for \(\mathrm{NH}_{3}\) and \(\mathrm{H}_{2} \mathrm{~S}\) taken together) is 0.614 atm. What is \(K_{p}\) for this equilibrium at \(24^{\circ} \mathrm{C}\) ?

Text Transcription:

NH_4 SH

24^circ C

NH_4 SH(s) \rightleftharpoons NH_3(g)+H_2 S(g)

NH_3

H_2 S

K_p

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