?The hydrogen halides have the following fundamental vibrational wavenumbers: 4141.3

Chapter 11, Problem E11C.4(a)

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The hydrogen halides have the following fundamental vibrational wavenumbers: 4141.3 \(\mathrm{cm}^{-1}\) (\({ }^{1} \mathrm{H}^{19} \mathrm{~F}\)); 2988.9 \(\mathrm{cm}^{-1}\) (\({ }^{-1} \mathrm{H}^{35} \mathrm{Cl}\)); 2649.7 \(\mathrm{cm}^{-1}\) (\({ }^{1} \mathrm{H}^{81} \mathrm{Br}\)); 2309.5 cm−1 (\(\mathrm{H}^{127} \mathrm{I}\)). Calculate the force constants of the hydrogen–halogen bonds.

Text Transcription:

cm^-1

^1H^19F

^-1H^35Cl

^1H^81Br

H^127I

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