?For a binary system derive the expression for \(H^{E}\) implied by the Wilson equation

Chapter 13, Problem 13.62

(choose chapter or problem)

For a binary system derive the expression for \(H^{E}\) implied by the Wilson equation for \(G^{E} / R T\). Show that the implied excess heat capacity \(C_{P}^{E}\) is necessarily positive. Recall that the Wilson parameters depend on T, in accord with Eq. (13.53).

Text Transcription:

H^E

G^E/RT

C_P^E

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