?The following equations of state are occasionally used for approximate calculations on

Chapter 1, Problem P1C.18

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The following equations of state are occasionally used for approximate calculations on gases: (gas A) \(p V_{\mathrm{m}}=R T\left(1+b / V_{\mathrm{m}}\right)\), (gas B) \(p\left(V_{\mathrm{m}}-b\right)=R T\). Assuming that there were gases that actually obeyed these equations of state, would it be possible to liquefy either gas A or B? Would they have a critical temperature? Explain your answer.

Text Transcription:

pV_m = RT(1 + b/V_m)

p(V_m − b) = RT.

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