?The exchange-current density for a \(\mathrm{Pt} \mid \mathrm{Fe}^{3+}\)

Chapter 19, Problem E19D.5(b)

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The exchange-current density for a \(\mathrm{Pt} \mid \mathrm{Fe}^{3+}\) , \(\mathrm{Fe}^{2+}\) electrode is \(2.5 \mathrm{\ mA} \mathrm{\ cm}^{-2}\) . The standard potential of the electrode is +0.77 V. Derive an expression for the current flowing through an electrode of surface area \(1.0 \mathrm{\ cm}^{2}\) as a function of the potential applied to the electrode; assume standard conditions.

Text Transcription:

Pt mid Fe^3+

Fe^2+

2.5 mA cm^-2

1.0 cm^2

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