?Calculate Z and V for boron trichloride at 300 K and 1.5 bar by the following

Chapter 3, Problem 3.48

(choose chapter or problem)

Calculate Z and V for boron trichloride at 300 K and 1.5 bar by the following equations:

(a) The truncated virial equation [Eq. (3.38)] with the following values of virial coefficients:

\(B = −724 cm^{3} \cdot mol^{−1}\)     \(C = −93,866 cm^{6} \cdot mol^{−2}\)

(b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)]

(c) The Redlich/Kwong equation

(d) The Soave/Redlich/Kwong equation

(e) The Peng/Robinson equation

For \(BCl_{3}\), \(T_{c} = 452 K\), \(P_{c} = 38.7 bar\), and ω = 0.086.

Text Transcription:

BCl_3

T_c = 452 K

P_c = 38.7 bar