?Calculate the molar volume of saturated liquid and the molar volume of saturated vapor

Chapter 3, Problem 3.53

(choose chapter or problem)

Calculate the molar volume of saturated liquid and the molar volume of saturated vapor by the Redlich/Kwong equation for one of the following and compare results with values found by suitable generalized correlations.

(a) Propane at 40°C where \(P^{sat}\) = 13.71 bar

(b) Propane at 50°C where \(P^{sat}\) = 17.16 bar

(c) Propane at 60°C where \(P^{sat}\) = 21.22 bar

(d) Propane at 70°C where \(P^{sat}\) = 25.94 bar

(e) n-Butane at 100°C where  \(P^{sat}\) = 15.41 bar

(f ) n-Butane at 110°C where  \(P^{sat}\) = 18.66 bar

(g) n-Butane at 120°C where  \(P^{sat}\) = 22.38 bar

(h) n-Butane at 130°C where  \(P^{sat}\) = 26.59 bar

(i) Isobutane at 90°C where  \(P^{sat}\) = 16.54 bar

(j) Isobutane at 100°C where  \(P^{sat}\) = 20.03 bar

(k) Isobutane at 110°C where  \(P^{sat}\) = 24.01 bar

(l) Isobutane at 120°C where  \(P^{sat}\) = 28.53 bar

(m) Chlorine at 60°C where  \(P^{sat}\) = 18.21 bar

(n) Chlorine at 70°C where  \(P^{sat}\) = 22.49 bar

(o) Chlorine at 80°C where  \(P^{sat}\) = 27.43 bar

(p) Chlorine at 90°C where  \(P^{sat}\) = 33.08 bar

(q) Sulfur dioxide at 80°C where  \(P^{sat}\) = 18.66 bar

(r) Sulfur dioxide at 90°C where  \(P^{sat}\) = 23.31 bar

(s) Sulfur dioxide at 100°C where  \(P^{sat}\) = 28.74 bar

(t) Sulfur dioxide at 110°C where  \(P^{sat}\) = 35.01 bar

(u) Boron trichloride at 400 K where  \(P^{sat}\) = 17.19 bar

For \(BCl_{3}\), \(T_{c} = 452 K\), \(P_{c} = 38.7 bar\), and ω = 0.086.

(v) Boron trichloride at 420 K where  \(P^{sat}\) = 23.97 bar

(w) Boron trichloride at 440 K where  \(P^{sat}\) = 32.64 bar

(x) Trimethylgallium at 430 K where  \(P^{sat}\) = 13.09 bar

For \(Ga(CH_{3})_{3}\), \(T_{c} = 510 K\), \(P_{c} = 40.4 bar\), and ω = 0.205.

(y) Trimethylgallium at 450 K where  \(P^{sat}\) = 18.27 bar

(z) Trimethylgallium at 470 K where  \(P^{sat}\) = 24.55 bar

Text Transcription:

P^sat

BCI_3

T_C = 452 K

P_C = 38.7 bar

GA(CH_3)_3

T_c = 510 K

P_c = 40.4 bar