?The data in Table 10.3 are experimental values of \(H^{E}\) for binary liquid mixtures

Chapter 10, Problem 10.33

(choose chapter or problem)

The data in Table 10.3 are experimental values of \(H^{E}\) for binary liquid mixtures of 1,2-dichloroethane(1) and dimethyl carbonate(2) at 313.15 K and 1(atm).

(a) Determine from the data numerical values of parameters a, b, and c in the correlating equation:

\(H^{E}=x_{1} x_{2}\left(a+b x_{1}+c x_{1}^{2}\right)\)

(b) Determine from the results of part (a) the minimum value of \(H^{E}\). At what value of \(x_{1}\) does this occur?

(c) Determine from the results of part (a) expressions for \(\bar{H}_{1}^{E} \text { and } \bar{H}_{2}^{E}\). Prepare a plot of these quantities vs. \(x_{1}\), and discuss its features.

Text Transcription:

H^E

H^E = x_1x_2 (a + bx_1 + cx_1^2)

x_1

bar H_1^E and bar H_2^E

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