When a NaF molecule makes a transition from the to the

Chapter 42, Problem 42.42

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When a NaF molecule makes a transition from the l = 3 to the l = 2 rotational level with no change in vibrational quantum number or electronic state, a photon with wavelength 3.83 mm is emitted. A sodium atom has mass \(3.82\times10^{-26}\mathrm{\ kg}\), and a fluorine atom has mass \(3.15\times10^{-26}\mathrm{\ kg}\). Calculate the equilibrium separation between the nuclei in a NaF molecule. How does your answer compare with the value for NaCl given in Section 42.1? Is this result reasonable? Explain.

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