Solution Found!
Compound X, isolated from lanolin (sheep’s wool fat), has
Chapter 1, Problem 33SP(choose chapter or problem)
Problem 33SP
Compound X, isolated from lanolin (sheep’s wool fat), has the pungent aroma of dirty sweatsocks. A careful analysis showed that compound X contains 62.0% carbon and 10.4% hydrogen. No nitrogen or halogen was found.
(a) Compute an empirical formula for compound X.
(b) A molecular weight determination showed that compound X has a molecular weight of approximately 117. Find the molecular formula of compound X.
(c) Many possible structures have this molecular formula. Draw complete structural formulas for four of them.
Questions & Answers
QUESTION:
Problem 33SP
Compound X, isolated from lanolin (sheep’s wool fat), has the pungent aroma of dirty sweatsocks. A careful analysis showed that compound X contains 62.0% carbon and 10.4% hydrogen. No nitrogen or halogen was found.
(a) Compute an empirical formula for compound X.
(b) A molecular weight determination showed that compound X has a molecular weight of approximately 117. Find the molecular formula of compound X.
(c) Many possible structures have this molecular formula. Draw complete structural formulas for four of them.
ANSWER:
Answer :
Step 1
(a) To write an empirical formula of the compound X.
62% means 62 gram carbon; 10.4 gram hydrogen;.
1. find the mole of each element:
mole C 62 g/12.01=5.17 mol
mole H 10.4/1.008=10.31 mol .
2. Divided each by the smallest number; 5.17mol is the smallest number from above to get our subscript.
C: 5.17/5.17=1
H: 10.31/5.17=2
The molecular formula of compound X is( CH2)
(b) A molecular weight determination showed that compound X has a molecular weight of approximately 117. Find the molecular formula of compound X.
The molecular formula of compound X we got is CH2 and molecular weight is 14 ,
=117/14.
=8.3
The molecular formula of the compound is (CH2)*8=C8H16.
(C) Many possible structures have this molecular formula. Draw complete structural formulas for four of them.
Possible structures of cyclo octane :
1)cis -2 octene
2)Z-2-octene