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Predict the multiplicity (the number of peaks as a result

Chapter 18, Problem 34SP

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QUESTION:

Predict the multiplicity (the number of peaks as a result of splitting) and the chemical shift for each shaded proton in the following compounds.

Equation Transcription:

Text Transcription:

CH_{3}-CH_{2}-CCl_{2}-CH_{3}

CH_{3}-CH-OH

CH_{3}

CH_{3}-CH-CH_{3}

CH_{3}

CH_{3}

CH_{3}-CH_{2}-C-O-CH_{2}-CH_{3}

CH_{3}

Questions & Answers

QUESTION:

Predict the multiplicity (the number of peaks as a result of splitting) and the chemical shift for each shaded proton in the following compounds.

Equation Transcription:

Text Transcription:

CH_{3}-CH_{2}-CCl_{2}-CH_{3}

CH_{3}-CH-OH

CH_{3}

CH_{3}-CH-CH_{3}

CH_{3}

CH_{3}

CH_{3}-CH_{2}-C-O-CH_{2}-CH_{3}

CH_{3}

ANSWER:

Solution 34SP

a)

Three types of protons are present in the molecule.

The multiplicity of hydrogen atoms in the given compound is as follows:

The chemical shift values for the given compound are as follows:

b)

Two types of protons are present in the molecule.

The multiplicity of hydrogen atoms in the given compound is as follows:

The chemical shift values for the given compound are as follows:

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