(a)Use the ideal gas law to show that, for an ideal gas at constant pressure, the

Chapter 13, Problem 98GP

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QUESTION:

Problem 98GP

(a)Use the ideal gas law to show that, for an ideal gas at constant pressure, the coefficient of volume expansion is equal to β = 1/T, where T is the temperature in kelvins. Compare to Table 13–1 for gases at T = 293 K. (b) Show that the bulk modulus (Section 9–5) for an ideal gas held at constant temperature is B = P, where P is the pressure.

Table 13–1

Material

Coefficient of Linear Expansion, α (C°)-1

Coefficient of Volume Expansion, β (C°)-1

Solids

Aluminum

25 × 10–6

75 × 10–6

Brass

19 × 10–6

56 × 10–6

Copper

17 × 10–6

50 × 10–6

Gold

14 × 10–6

42 × 10–6

Iron or steel

12 × 10–6

35 × 10–6

Lead

29 × 10–6

87 × 10–6

Glass (Pyrex®)

3 × 10–6

9 × 10–6

Glass (ordinary)

25 × 10–6

27 × 10–6

Quartz

0.4 × 10–6

1 × 10–6

Concrete and brick

≈12 × 10–6

≈36 × 10–6

Marble

1.4 – 3.5 × 10–6

4–10 × 10–6

Liquids

Gasoline

 

950 × 10–6

Mercury

 

180 × 10–6

Ethyl alcohol

 

1100 × 10–6

Glycerin

 

500 × 10–6

Water

 

210 × 10–6

Gases

Air (and most other gases at atmospheric pressure)

 

3400 × 10–6

Questions & Answers

QUESTION:

Problem 98GP

(a)Use the ideal gas law to show that, for an ideal gas at constant pressure, the coefficient of volume expansion is equal to β = 1/T, where T is the temperature in kelvins. Compare to Table 13–1 for gases at T = 293 K. (b) Show that the bulk modulus (Section 9–5) for an ideal gas held at constant temperature is B = P, where P is the pressure.

Table 13–1

Material

Coefficient of Linear Expansion, α (C°)-1

Coefficient of Volume Expansion, β (C°)-1

Solids

Aluminum

25 × 10–6

75 × 10–6

Brass

19 × 10–6

56 × 10–6

Copper

17 × 10–6

50 × 10–6

Gold

14 × 10–6

42 × 10–6

Iron or steel

12 × 10–6

35 × 10–6

Lead

29 × 10–6

87 × 10–6

Glass (Pyrex®)

3 × 10–6

9 × 10–6

Glass (ordinary)

25 × 10–6

27 × 10–6

Quartz

0.4 × 10–6

1 × 10–6

Concrete and brick

≈12 × 10–6

≈36 × 10–6

Marble

1.4 – 3.5 × 10–6

4–10 × 10–6

Liquids

Gasoline

 

950 × 10–6

Mercury

 

180 × 10–6

Ethyl alcohol

 

1100 × 10–6

Glycerin

 

500 × 10–6

Water

 

210 × 10–6

Gases

Air (and most other gases at atmospheric pressure)

 

3400 × 10–6

ANSWER:

Solution 98GP

Step 1 of 5

The objective here is to prove that the relation between the coefficient of volume expansion and Temperature T is given by,

at constant pressure. Also, we need to show that the Bulk modulus B is equal to the Pressure, B = P, at constant temperature.

Part (a)

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