Acetylene is hydrogenated to form ethane. The feed to the

Chapter 4, Problem 4.39

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QUESTION:

Acetylene is hydrogenated to form ethane. The feed to the reactor contains 1.50 mol H 2/mol CzHz (3) Calculate the stoichiometric reactant ratio (mol Hz react/mol C2Hz react) and the yield ratio (kmol CzH6 formed/kmol Hz react). (b) Determine the limiting reactant and calculate the percentage by which the other reactant is in excess. (c) Calculate the mass feed rate of hydrogen (kg/s) required to produce 4 X 106 metric tons of ethane per year, assuming that the reaction goes to completion and that the process operates for 24 hours a day, 300 days a year. (d) There is a definite drawback to running with one reactant in excess rather than feeding the reactants in stoichiometric proportion. What is it? [Hint: In the process of part (c), what does the reactor effluent consist of and what will probably have to be done before the product ethane can be sold or used?]

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QUESTION:

Acetylene is hydrogenated to form ethane. The feed to the reactor contains 1.50 mol H 2/mol CzHz (3) Calculate the stoichiometric reactant ratio (mol Hz react/mol C2Hz react) and the yield ratio (kmol CzH6 formed/kmol Hz react). (b) Determine the limiting reactant and calculate the percentage by which the other reactant is in excess. (c) Calculate the mass feed rate of hydrogen (kg/s) required to produce 4 X 106 metric tons of ethane per year, assuming that the reaction goes to completion and that the process operates for 24 hours a day, 300 days a year. (d) There is a definite drawback to running with one reactant in excess rather than feeding the reactants in stoichiometric proportion. What is it? [Hint: In the process of part (c), what does the reactor effluent consist of and what will probably have to be done before the product ethane can be sold or used?]

ANSWER:

Step 1 of 9

A limiting reactant in the reaction gets ‘exhausted wholly’ and ceases the reaction with no further formation of products. Comparison based on mole ratio helps to determine this reactant.

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