In the text, the equation was derived for gaseous

Chapter 17, Problem 90

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In the text, the equation was derived for gaseous reactions where the quantities in Q were expressed in units of pressure. We also can use units of mol/L for the quantities in Q, specifically for aqueous reactions. With this in mind, consider the reaction for which Ka 7.2 104 at 25C. Calculate G for the reaction under the following conditions at 25C. a. [HF] [H] [F] 1.0 M b. [HF] 0.98 M, [H] [F] 2.7 102 M c. [HF] [H] [F] 1.0 105 M d. [HF] [F] 0.27 M, [H] 7.2 104 M e. [HF] 0.52 M, [F] 0.67 M, [H] 1.0 103 M Based on the calculated G values, in what direction will the reaction shift to reach equilibrium for each of the five sets of conditions? 91. C

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