If wet silver carbonate is dried in a stream of hot air,

Chapter 17, Problem 103

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If wet silver carbonate is dried in a stream of hot air, the air must have a certain concentration level of carbon dioxide to prevent silver carbonate from decomposing by the reaction H for this reaction is 79.14 kJ/mol in the temperature range of 25 to 125C. Given that the partial pressure of carbon dioxide in equilibrium with pure solid silver carbonate is 6.23 103 torr at 25C, calculate the partial pressure of CO2 necessary to prevent decomposition of Ag2CO3 at 110.C. (Hint: Manipulate the equation in Exercise 71.) 104

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