Precipitation and Separation of Ions (Section)A

Chapter , Problem 75E

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Problem 75E

Precipitation and Separation of Ions (Section)

A solution contains three anions with the following concentrations:

0.20 M Cr042- 0.10 M C032-, and 0.010 M CI-. If a dilute AgN03 solution is slowly added to the solution, what is the first compound to precipitate: Ag2Cr04 (Ksp = 1.2 x 10-12), Ag2C03 (Ksp = 8.1 x 10-12), or AgCl (Ksp = 1.8 x 10-10)?

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