Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid with

Chapter 15, Problem 15.141

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Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid with NaOH, stoichiometric points occur at pH 5 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (See Exercise 113.)

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