Consider the following equilibrium process: Predict the

Chapter 15, Problem 63QP

(choose chapter or problem)

Consider the following equilibrium process:

\(\mathrm{PCl}_{5}(\mathrm{g}) \rightleftarrows \mathrm{PCl}_{3}(\mathrm{g})+\mathrm{Cl}_{2}(\mathrm{g})\)  \(\Delta H^{\circ}=92.5 \mathrm{kJ} / \mathrm{mol}\)

Predict the direction of the shift in equilibrium when (a) the temperature is raised, (b) more chlorine gas is added to the reaction mixture, (c) some \(\mathrm{PCl}_{3}\) is removed from the mixture, (d) the pressure on the gases is increased, (e) a catalyst is added to the reaction mixture.

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