How many moles and numbers of ions of each type are

Chapter 4, Problem 15P

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QUESTION:

How many moles and numbers of ions of each type are present in the following aqueous solutions?

(a) \(88 \mathrm{~mL}\) of \(1.75 \mathrm{M}\) magnesium chloride

(b) \(321 \mathrm{~mL}\) of a solution containing \(0.22 \mathrm{~g}\) aluminum sulfate/ \(\mathrm{L}\)

(c) \(1.65 \mathrm{~L}\) of a solution containing \(8.83 \times 10^{21}\) formula units of cesium nitrate per liter

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QUESTION:

How many moles and numbers of ions of each type are present in the following aqueous solutions?

(a) \(88 \mathrm{~mL}\) of \(1.75 \mathrm{M}\) magnesium chloride

(b) \(321 \mathrm{~mL}\) of a solution containing \(0.22 \mathrm{~g}\) aluminum sulfate/ \(\mathrm{L}\)

(c) \(1.65 \mathrm{~L}\) of a solution containing \(8.83 \times 10^{21}\) formula units of cesium nitrate per liter

ANSWER:

Here we have to calculate how many moles and numbers of ions of each type are present in the following aqueous solutions.

 

Step 1 of 6

 

(a) \(88 \mathrm{~mL}\) of \(1.75 \mathrm{M}\) magnesium chloride

1st we have to write the chemical reaction for the dissociation of \(\mathrm{AlCl}_{3}\) (aluminum chloride)

\(\mathrm{MgCl}_{2}(\mathrm{~s}) \rightarrow \mathrm{Mg}^{2+}(\mathrm{aq})+2 \mathrm{Cl}^{-}(\mathrm{aq})\)

In the above reaction it has been found that \(1 \mathrm{~mol}\) of \(\mathrm{Mg}^{2+}\) and \(2 \mathrm{~mole}\) of \(\mathrm{Cl}^{-}\) is dissolved per mole of \(\mathrm{MgCl}_{2}\)

In this question it has been given that molarity of \(\mathrm{MgCl}_{2}\) is \(1.75 \mathrm{M}\) and volume is \(88 \mathrm{~mL}\).

Mole of \(\mathrm{Gg}^{2+}\) formed from \(\mathrm{MgCl}_{2}:-\)

\(88 \mathrm{~mL}\) of \(\times \frac{1 L}{1000 \mathrm{~mL}} \times \frac{1.75 \mathrm{MMgCl}_{2}}{L} \times \frac{1 \text { molof } M g^{2+}}{1 \operatorname{mol} M g C l_{2}}\) \(=0.154 \mathrm{~mol}\) of \(\mathrm{Mg}^{2+}\)

Mole of \(\mathrm{Cl}^{-}\) formed fom \(\mathrm{MgCl}_{2}:\)

\(\begin{aligned}&88 \mathrm{~mL} \text { of } \times \frac{1 L}{1000 \mathrm{~mL}} \times \frac{0.45 \mathrm{MMgCl}_{2}}{L} \times \frac{2 \operatorname{molofCl}^{-}}{1 \mathrm{~mol} \mathrm{MgCl}_{2}} \\&=0.079 \mathrm{~mol} \text { of } \mathrm{Cl}^{-}\end{aligned}\)

 

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